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Progress in Chemistry 2006, Vol. 18 Issue (0708): 849-853   Next Articles

• Review •

Catalytic Applications of the Mesoporous Materials in Epoxidation of Olefins

Xuefeng Li1;Huanxin Gao2;Qingling Chen1,2*   

  1. 1. Department of Chemistry and Pharmacy, East China University of Science and Technology, Shanghai 200237, China; 2. Shanghai Research Institute of Petrochemical Technology, Shanghai 201208, China
  • Received: Revised: Online: Published:
  • Contact: Qingling Chen
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The catalytic applications of the mesoporous materials in epoxidation of olefins are summarized, including the preparation methods and modification of the materials, catalytic performance and characterization of active sites. High dispersion of tetra-coordinated titanium is achieved by means of adjusting optimal combination of titanium and silicon atoms, hence the activity of the materials can be improved. On the other hand, the activity and selectivity can also be greatly promoted by silylation due to the enhancement of the surface hydrophobicity of the materials. The framework titanium atoms and their coordination state can be characterized by spectroscopic technologies and the molecular simulation.
Key words: mesoporous materials, alkene epoxidation, catalysis

CLC Number: 

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