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Progress in Chemistry 2006, Vol. 18 Issue (06): 768-779 Previous Articles   Next Articles

• Review •

Recent Progress in pH/Temperature-Responsive Amphiphilic Block Copolymers

Qun Zhao;Peihong Ni**   

  1. School of Chemistry and Chemical Engineering, Soochow University, The Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou 215123, China
  • Received: Revised: Online: Published:
  • Contact: Peihong Ni
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The stimuli-responsive amphiphilic block copolymers have drawn much attention due to their various promising potential applications. The pH and temperature responsive block copolymers are considerably important because they are relatively convenient to be synthesized and sensitive to outer stimuli. This review focuses on recent progress in stimuli-responsive and amphiphilic block copolymers containing polymethacrylates, poly(ethylene oxide) (PEO), and poly(propylene oxide) (PPO),which are prepared by various controlled/living polymerizations. The pH/temperatureresponsive properties of these copolymers in aqueous solution are also summarized.

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[ 1 ] 邱利焱(Qiu L Y) , 朱康杰( Zhu K J ) 1 高分子学报(Acta Polymeric Sinica) , 2003 , (6) : 387 —392
[ 2 ] 马俊涛(Ma J T) , 赵林(Zhao L) , 黄荣华(Huang R H) . 化学世界(Chemical World) , 2001 , (11) : 608 —614
[ 3 ] Gil E S , Hudson S A. Prog. Polym. Sci . , 2004 , 29 ( 12) :1173 —1222
[ 4 ] Jeong B , Gutowska A. Trends Biotechnol . , 2002 , 20(7) : 305 —311
[ 5 ] Galaev I Y, Mattiasson B. Trends Biotechnol . , 1999 , 17 : 335 —340
[ 6 ] Liu Q Q , Yu Z Q , Ni P H. Colloid Polym. Sci . , 2004 , 282(4) :387 —393
[ 7 ] Dai S , Ravi P , Tam K C , et al . Langmuir , 2003 , 19 (12) :5175 —5177
[ 8 ] Konno T , Kurita K, Iwasaki Y, et al . Biomaterials , 2001 , 22(13) : 1883 —1889
[ 9 ] Iwasaki Y, Nakabayashi N , Ishihara K. J . Biomed. Mater.Res. , 2001 , 57(1) : 72 —78
[10] Ma Y H , Tang Y Q , Billingham N C , et al . Macromolecules ,2003 , 36(10) : 3475 —3484
[11] Castelletto V , Hamley I W, Ma Y, Bories-Azeau X, et al .Langmuir , 2004 , 20(10) : 4306 —4309
[12] Ma Y H , Tang Y Q , Billingham N C , et al . Biomacromolecules ,2003 , 4(4) : 864 —868
[13] Licciardi M, Tang Y, Billingham N C , et al . Biomacromolecules ,2005 , 6(2) : 1085 —1096
[14] Yusa S , Fukuda K, Yamamoto T , et al . Biomacromolecules ,2005 , 6(2) : 663 —670
[15] Stenzel M H , Barner-Kowollik C , Davis T P , et al . Macromol .Biosci . , 2004 , 4 : 445 —453
[16] Tang Y Q , Liu S Y, Armes S P , et al . Biomacromolecules ,2003 , 4 (6) : 1636 —1645
[17] Gohy J F , Willet N , Varshney S , et al . Angew. Chem. Int .Ed. , 2001 , 40(17) : 3214 —3216
[18] Gohy J , Lohmeijer B G G, Varshney S K, et al . Macromolecules ,2002 , 35(26) : 9748 —9755
[19] Bütün V , Wang X S , Báìez MV , et al . Macromolecules , 2000 ,33(1) : 1 —3
[20] Liu S Y, Weaver J V M, Tang Y Q , et al . Macromolecules ,2002 , 35(16) : 6121 —6131
[21] Weaver J V M, Tang Y Q , Liu S Y, et al . Angew. Chem. Int .Ed. , 2004 , 43(11) : 1389 —1392
[22] Liu S Y, Weaver J V M, Save M, et al . Langmuir , 2002 , 18(22) : 8350 —8357
[23] Hrub? M, Koňák C , Ulbrich K. J . Control . Release , 2005 , 103(1) : 137 —148
[24] Liu S Y, Armes S P. Angew. Chem. Int . Ed. , 2002 , 41 (8) :1413 —1416
[25] Vamvakaki M, Papoutsakis L , Katsamanis V , et al . Faraday Discussions , 2005 , 128 : 129 —147
[26] Iijima M, Nagasaki Y, Kato M, et al . Polymer , 1997 , 38 (2) :1197 —1202
[27] Báìez M V P , Robinson K L , Bütün V , et al . Polymer , 2001 , 42(1) : 29 —37
[28] Zhao Q , Ni P H. Polymer , 2005 , 46 (9) : 3141 —3148
[29] Lascelles S F , Malet F , Mayada R , et al . Macromolecules , 1999 ,32(8) : 2462 —2471
[30] 倪沛红(Ni P H) , 潘祺晟(Pan Q S) , 府寿宽(Fu S K) . 高等学校化学学报(Chem. J . Chinese Univ. ) , 2002 , 23 (4) :748 —750
[31] Virtanen J , Arotaréna M, Heise B , et al . Langmuir , 2002 , 18(14) : 5360 —5365
[32] Arotaréna M,Heise B , Ishaya S , et al . J . Am. Chem. Soc. ,2002 , 124 (14) : 3787 —3793
[33] Weaver J V M, Armes S P , Bütün V. Chem. Commun. , 2002 ,18 : 2122 —2123
[34] Jeong B , Bae Y H , Kim S W. Macromolecules , 1999 , 32 (21) :7064 —7069
[35] Jeong B , Lee D S , Shon J , et al . J . Polym. Sci . Part A: Polym.Chem. , 1999 , 37(6) : 751 —760
[36] Jeong B , Bae Y H , Lee D S , et al . Nature , 1997 , 388 : 860 —862
[37] Park S Y, Han B R , Na K M, et al . Macromolecules , 2003 , 36(11) : 4115 —4124
[38] Lee S B , Russell A J , Matyjaszewski K. Biomacromolecules ,2003 , 4(5) : 1386 —1393
[39] Sugihara S , Kanaoka S , Aoshima S. J . Polym. Sci . Part A:Polym. Chem. , 2004 , 42 (11) : 2601 —2611
[40] Sugihara S , Hashimoto K, Okabe S , et al . Macromolecules ,2004 , 37(2) : 336 —343
[41] Aoshima S , Sugihara S. J . Polym. Sci . Part A: Polym. Chem. ,2000 , 38(21) : 3962 —3965
[42] Okabe S , Sugihara S , Aoshima S , et al . Macromolecules , 2002 ,35(21) : 8139 —8146
[43] Okabe S , Sugihara S , Aoshima S , et al . Macromolecules , 2003 ,36(11) : 4099 —4106
[44] Sugihara S , Hashimoto K, Matsumoto Y, et al . J . Polym. Sci .Part A: Polym. Chem. , 2003 , 41(21) : 3300 —3312
[45] Topp M D C , Dijkstra P J , Talsma H , et al . Macromolecules ,1997 , 30(26) : 8518 —8520
[46] Topp M D C , Leunen H , Dijkstra P J , et al . Macromolecules ,2000 , 33(14) : 4986 —4988
[47] Virtanen J , Holappa S , Lemmetyinen H , et al . Macromolecules ,2002 , 35(12) : 4763 —4769
[48] Hales M, Barner-Kowollik C , Davis T P , et al . Langmuir , 2004 ,20(25) : 10809 —10817
[49] Yusa S , Shimada Y, Mitsukami Y, et al . Macromolecules , 2004 ,37(20) : 7507 —7513
[50] Lowe A B , Billingham N C , Armes S P. Macromolecules , 1998 ,31(18) : 5991 —5998
[51] Lowe A B , Billingham N C , Armes S P. Chem. Commun. ,1997 , 1035 —1036
[52] Ravi P , Dai S , Tan C H , et al . Macromolecules , 2005 , 38 (3) :933 —939
[53] Tan C H , Ravi P , Dai S , et al . Langmuir , 2004 , 20 ( 23) :9901 —9904
[54] Dai S , Ravi P , Tan C H , et al . Langmuir , 2004 , 20 (20) :8569 —8575
[55] Teoh S K, Ravi P , Dai S , et al . J . Phys. Chem. B , 2005 , 109(10) : 4431 —4438
[56] Francis R , Lepoittevin B , Taton D , et al . Macromolecules ,2002 , 35(24) : 9001 —9008
[57] Feng X S , Pan C Y. Macromolecules , 2002 , 35 (13) : 4888 —4893
[58] Li Y G, Shi P J , Zhou Y S , et al . Polym. Int . , 2004 , 53 :349 —354
[59] Cai Y L , Tang Y, Armes S P. Macromolecule , 2004 , 37 (26) :9728 —9737
[60] Cai Y L , Burguiere C , Armes S P. Chem. Commun. , 2004 ,802 —803
[61] Ni P H , Cao X Y, Yan D Y, et al . Chinese Science Bulletin ,2002 , 47(4) : 280 —283
[62] Ni P H , Pan Q S , Zha L S , et al . J . Polym. Sci . Part A:Polym. Chem. , 2002 , 40(4) : 624 —631
[63] Vamvakaki M, Billingham N C , Armes S P. Macromolecules ,1999 , 32 (6) : 2088 —2090
[64] Anderson B C , Cox S M, Bloom P D , et al . Macromolecules ,2003 , 36(5) : 1670 —1676
[65] Agarwal A , Unfer R , Mallapragada S K. J . Control . Release ,2005 , 103 (1) : 245 —258
[66] Liu S Y, Billingham N C , Armes S P. Angew. Chem. Int . Ed. ,2001 , 40(12) : 2328 —2331
[67] Weaver J V M, Bannister I , Robinson K L , et al .Macromolecules , 2004 , 37(7) : 2395 —2403
[68] Bütün V , Billingham N C , Armes S P. J . Am. Chem. Soc. ,1998 , 120 (45) : 11818 —11819
[69] Bütün V , Armes S P , Billingham N C , et al . Macromolecules ,2001 , 34(5) : 1503 —1511
[70] Lee A S , Gast A P , Bütün V , et al . Macromolecules , 1999 , 32(13) : 4302 —4310
[71] Bütün V , Armes S P , Billingham N C. Polymer , 2001 , 42(14) :5993 —6008
[72] Lee A S , Bütün V , Vamvakaki M, et al . Macromolecules , 2002 ,35(22) : 8540 —8551
[73] Bütün V , Armes S P , Billingham N C. Macromolecules , 2001 ,34 (5) : 1148 —1159
[74] Liu S Y, Armes S P. Langmuir , 2003 , 19(10) : 4432 —4438
[75] Bütün V , Vamvakaki M, Billingham N C , et al . Polymer , 2000 ,41(9) : 3173 —3182

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