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Progress in Chemistry 2006, Vol. 18 Issue (06): 752-760 Previous Articles   Next Articles

• Review •

Transition-Metal Catalyzed α-Arylation of Carbonyl Derivatives and Compounds with Acidic Hydrogen

Junfang Gong;Chen Xu;Yangjie Wu**   

  1. Department of Chemistry, Zhengzhou University, Zhengzhou 450052, China
  • Received: Revised: Online: Published:
  • Contact: Yangjie Wu
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Advances in the transition-metal catalyzed α-arylation of carbonyl derivatives and compounds with acidic hydrogen are reviewed. By using sterically hindered, electron-rich alkylphosphines and N-heterocyclic carbenes(NHC), this process has encompassed a broad range of substrates including ketones, aldehydes, esters, amides, malonates, nitrocompounds, nitriles and sulfones.
Key words: palladium-catalysis, α-arylation, carbonyl derivatives, acidic hydrogen, aryl halides, phosphine ligands, NHC ligands

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