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Progress in Chemistry 2006, Vol. 18 Issue (05): 550-555 Previous Articles   Next Articles

• Review •

SeleniumCatalyzed Reduction of Nitrobenzenes with CO/H2O Affording Aniline

Xiaozhi Liu Shiwei Lu   

  1. Chemical Institute of Rare and Scattered Metals,Liaoning University;National Engineering Research Center for Catalysis,Dalian Institute of Chemical Physics National Engineering Research Center for Catalysis,Dalian Institute of Chemical Physics,Chinese Academy of Sciences
  • Received: Revised: Online: Published:
  • Contact: Shiwei Lu
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Reduction of nitrobenzenes to prepare anilines is an important process. The progress of the selenium-catalyzed of nitrobenzenes with CO/H2O to prepare anilines is reviewed in detail. The process of selenium-catalyzed reduction with CO/H2O from high pressure reaction to atmospheric reaction is introduced. It is pointed out that the selenium-catalyzed reduction of nitrobenzenes with CO/H2O to prepare anilines in atmosphere is a convenient and environmentally benign method.
Key words: selenium catalyst, reduction, nitrobenzene, aniline

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