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Progress in Chemistry 2006, Vol. 18 Issue (04): 362-381   Next Articles

• Review •

Phase Separation Kinetics and Pattern Formation and Selection in Polymer Systems

Yuliang Yang**;Feng Qiu;Ping Tang;Hongdong Zhang   

  1. The Key Laboratory of Molecular Engineering of Polymers, Ministry of Education,Department of Macromolecular Science, Fudan University, Shanghai 200433, China
  • Received: Revised: Online: Published:
  • Contact: Yuliang Yang
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Most of polymer blends are thermodynamic immiscible because of small entropy of mixing, forming unique spatial-temporal pattern. In this review, based on our recent work, we  focus on the phase separation kinetics and corresponding pattern evolution of polymer system by using time dependent Ginzberg-Landau (TDGL) equation. The review contents cover the phase separation dynamics under shear for polymer blends and block copolymers, phase separation coupling with chemical reactions, and phase separation on the spherical surface. Also microphase separation dynamics of complex triblock copolymers is reviewed by means of the coupling between the TDGL and self-consistent field theory (SCFT), namely dynamic SCFT, which consider both the dynamics and the topological characteristic of the chain.
Key words: TDGL equation, shear, block copolymer, chemical reactions, differential geometry of curved space, dynamic self-consistent field theory

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[ 1 ] 冯端(Feng D) , 金国钧(Jin G J ) . 凝聚态物理新论(New Perspective on Condensed Matter Physics) . 上海(Shanghai) : 上海科技出版社( Shanghai Scientific & Technical Publishers) ,1992
[ 2 ] Flory P J . Principles of Polymer Chemistry. Ithaca and London :Cornell Univ. Press , 1953
[ 3 ] Brown G, Chakrabarti A. J . Chem. Phys. , 1993 , 98 : 2451 —2458
[ 4 ] Olabisi O , Robeson L M, Shaw M T. Polymer-Polymer Miscibility. London : Academic Press , 1978
[ 5 ] Cahn J W. J . Chem. Phys. , 1965 , 42 : 93 —99
[ 6 ] Reister E , Müller M, Binder K. Phys. Rev. E , 2001 , 64 :041804
[ 7 ] De Gennes P G. Scaling Concept in Polymer Physics. Ithaca and London : Cornell Univ. Press , 1979
[ 8 ] De Gennes P G. J . Chem Phys. , 1980 , 72 : 4756 —4763
[ 9 ] Bray A J . Adv. Phys. , 1994 , 43 : 357 —459
[10] 韩志超( Han Z C) . 结构材料化学进展( Advances in ConstructionMaterial ) . 北京( Beijing) : 化学工业出版社(Chem. Industry Press) , 2005. 290 —326
[11] Hohenberg P C , Halperin B I. Rev. Mod. Phys. , 1977 , 49 :435 —479
[12] Qiu F , Ding J D , Yang Y L. Phys. Rev. E , 1998 , 58 : R1230
[13] Qiu F , Zhang H D , Yang Y L. J . Chem. Phys. , 1998 , 109 :1575 —1583
[14] Oono Y, Puri S. Phys. Rev. Lett . , 1987 , 58 : 836 —839
[15] Zhang Z L , Zhang H D , Yang Y L , et al . Macromolecules ,2001 , 34 : 1416 —1429
[16] Ohta T, Nozaki H , Doi M. J . Chem. Phys. , 1990 , 93 : 2664 —2675
[17] Vinckier I , Laun H M. Rheol . Acta , 1999 , 38 : 274 —286
[18] Gronski W, Lauger J , Laubner C. J . Mol . Struct . , 1996 , 383 :23 —30
[19] Zhang Z L , Zhang H D , Yang Y L. J . Chem. Phys. , 2000 ,113 : 8348 —8361
[20] Zhang Z L , Zhang H D , Yang Y L. J . Chem. Phys. , 2001 ,115 : 7783 —7792
[21] Ohta T, Kawasaki K. Macromolecules , 1986 , 19 : 2621 —2632
[22] Luo K F , Yang Y L. Polymer , 2004 , 45 : 6745 —6751
[23] Luo K F , Yang Y L. Macromolecules , 2002 , 35 : 3722 —3730
[24] Hashimoto T, Itakura M, Hasegawa H. J . Chem. Phys. , 1986 ,85 : 6118 —6128
[25] Tanaka H. Phys. Rev. Lett . , 1996 , 76 : 787 —790
[26] Clarke N , McLeish T C B , Pavawongsak S , et al .Macromolecules , 1997 , 30 : 4459 —4463
[27] Zhang H D , Zhang J W, Yang Y L. Macromol . Theory Simul . ,1995 , 4 : 1001 —1013
[28] Zhang J N , Zhang Z L , Zhang H D , et al . Phys. Rev. E , 2001 ,64 : 051510
[29] 张家宁( Zhang J N) . 复旦大学博士学位论文( Ph D Dissrtation of Fudan Univ. ) , 2002
[30] Imaeda T, Furakawa A , Onuki A. Phys. Rev. E , 2005 , 70 :051503
[31] Hobbie E K, Kim S , Han C C. Phys. Rev. E , 1996 , 54 : R5909
[32] Matsuzaka K, Koga T, Hashimoto T. Phys. Rev. Lett . , 1998 ,80 : 5441 —5444
[33] Qiu F , Zhang H D , Yang Y L. J . Chem. Phys. , 1998 , 108 :9529 —9536
[34] Luo K F , Zhang H D , Yang Y L. Macromol . Theory Simul . ,2004 , 13 : 335 —344
[35] Pistoor N , Binder K. Colloid &Polym. Sci . , 1988 , 266 : 132 —140
[36] Luo K F , Yang YL. J . Chem. Phys. , 2001 , 115 : 2818 —2826
[37] O’Shaughnessy B , Vavylonis D. Macromolecules , 1999 , 32 :1785 —1796
[38] Okada M, Sakaguchi T. Macromolecules , 1999 , 32 : 4154 —4156
[39] Corberi F , Gonnella G, Lamura A. Phy. Rev. Lett . , 1998 , 81 :3852 —3855
[40] Tran-Cong Q , Kawai J , Nishikawa Y, et al . Phys. Rev. E ,1999 , 60 : R1150
[41] Tong C H , Yang YL. J . Chem. Phys. , 2002 , 116 ; 1519 —1529
[42] Liu B , Tong C H , Yang YL. J . Phys. Chem. B , 2001 , 105 :10091 —10100
[43] Tong C H , Zhang H D , Yang YL. J . Phys. Chem. B , 2002 ,106 : 7869 —7877
[44] Schoenborn O , Desai R C. J . Statistical Phys. , 1999 , 95 : 949 —979
[45] Schonborn O , Desai R C. Physica A , 1997 , 239 : 412 —419
[46] Schonborn O L , Desai R C. Euro. Phys. J . B , 1999 , 9 : 719 —724
[47] Saxena A , Lookman T. Physica D , 1999 , 133 : 416 —426
[48] Jiang Y, Lookman T, Saxena A. Phys. Rev. E , 2000 , 61 :R57 —R60
[49] Tang P , Qiu F , Zhang H D , et al . Phys. Rev. E , 2005 , 72 :016710
[50] Jarrold M F. Nature , 2000 , 407 : 26 —27
[51] Meyer M, Desbrun M, Schroder P , et al . VisMath Proceedings ,Berlin , Germany , 2002 , http://multires.caltech.edu/pubsd/diffGeorOps.pdf
[52] 李荣华(Li R H) . 吉林大学自然科学学报(Acta Scientiarum Naturalium Universitatis Jilinensis) , 1995 , 1 : 14 —22
[53] GomatamJ , Amdjadi F. Phys. Rev. E , 1997 , 56 : 3913 —3919
[54] Bausch A R , Bowick M J , Cacciuto A , et al . Science , 2003 ,299 : 1716 —1718
[55] Fraaije J G E M. J . Chem. Phys. , 1993 , 99 : 9202 —9212
[56] Morita H , Kawakatsu T, Doi M. Macromolecules , 2001 , 34 :8777 —8783
[57] Helfand E. J . Chem. Phys. , 1975 , 62 : 999 —1005
[58] Edwards S F. Proc. Phys. Soc. , 1965 , 85 : 613 —624
[59] Morita H , Kawakatsu T, Doi M, et al . Macromolecules , 2002 ,35 : 7473 —7480
[60] Ferreira P G, Ajdari A , Leibler L. Macromolecules , 1998 , 31 :3994 —4003
[61] Xia J F , Sun M Z, Qiu F , et al . Macromolecules , 2005 , 38 :9324 —9332
[62] 夏建峰(Xia J F) , 邱枫(Qiu F) , 张红东(Zhang H D) , et al .化学学报(Acta Chim. Sinica) , 2005 , 63 : 1109 —1115
[63] Matsen M W, Bates F S. J . Chem. Phys. , 1997 , 106 : 2436 —2448
[64] Zhang H D , Zhang J W, Yang Y L. J . Chem. Phys. , 1997 ,106 : 784 —792
[65] Lin Z Q , Zhang H D , Yang Y L. Macromol . Theory Simul . ,1997 , 6 : 1153 —1168
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