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Progress in Chemistry 2006, Vol. 18 Issue (0203): 142-158 Previous Articles   Next Articles

• Review •

Dynamical Size Effect in Mesoscopic Chemical Reaction Systems*

Zhonghuai Hou;Houwen Xin**   

  1. Department of Chemical Physics, University of Science and Technology of China,Hefei 230026,China 
  • Received: Revised: Online: Published:
  • Contact:

    Houwen Xin

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The effect of internal noise on mesoscopic chemical dynamics is studied using stochastic simulation and hemical Langevin equations, with special focus on surface catalytic systems and life systems. It is found that internal noise can induce chemical oscillations, in a parameter region subthreshold to deterministic oscillatory dynamics. Specifically, the strength of the noise induced oscillation undergoes one or multiple maxima with the variation of the system size or number of total molecules, and the maximum values can be considerably enhanced when the dynamical elements are coupled together. Such phenomena demonstrate a possible new mechanism of size effect in mesoscopic chemical systems.
Key words: mesoscopic chemistry, nonlinear chemical dynamics, intrinsic noise, size effect

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