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Progress in Chemistry 2005, Vol. 17 Issue (06): 1041-1047 Previous Articles   Next Articles

• Review •

Progress of Synthesis and Applications of Organoaluminacycles

Fang Hongyun;Xi Zhenfeng**   

  1. College of Chemistry &Molecular Engineering,Peking University,Beijing 100871,China
  • Received: Revised: Online: Published:
  • Contact: Xi Zhenfeng
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Recent progress of synthesis and applications of organoaluminacycles is summarized. As synthetic methods for organoaluminacycles,carboalumination or hydroalumination of alkynes followed by thermal elimination,reaction of di2organolithium reagents with aluminum halides,and zirconocene2catalyzed reactions of alkynes with AlR3 have been developed.Useful synthetic reactions of organoaluminacycles ,such as reactions with a variety of electrophiles,alkylation reagents,and metal2mediated coupling reactions are presented.
Key words: organoaluminacycles, synthesis, applications

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