中文
Earlier issues
Announcement
More
Progress in Chemistry 2005, Vol. 17 Issue (04): 706-715 Previous Articles   Next Articles

• Review •

Preparation of Polycarbonate Directly from Carbon Dioxide and Epoxides

Xiao Linfei;Li Fuwei;Xia Chungu**   

  1. State Key Laboratory of Oxo Synthesis and Seletive Oxidation, Lanzhou Institute of Chemical Physics, The Chinese Academy of Sciences,Lanzhou 730000,China
  • Received: Revised: Online: Published:
  • Contact: Xia Chungu
PDF ( 2715 ) Cited
Export

EndNote

Ris

BibTeX

The latest progress in the research of polycarbonate synthesis directly from carbon dioxide and epoxides is reviewed. The catalytic reaction mechanism is discussed in detail. Polycarbonate synthesized from carbon dioxide and epoxides has much significance in polymer synthetic chemistry, utilization of carbon resources and environment protection. It provides potential applications for polycarbonate produce.
Key words: carbon dioxide, epoxides, alternating copolymerization, polycarbonates, catalysts, reaction mechanism

CLC Number: 

[ 1 ] Kacholia K, Reck R A. Climate Changes , 1997 , 35 : 53
[ 2 ] Broeeker W S. Science , 1997 , 278 : 1582
[ 3 ] Meehl G A. Washington W M. Nature , 1996 , 382 : 56
[ 4 ] Santer B D , Jaylor K E , Wigley T M L. et al . Nature , 1996 ,382 : 39
[ 5 ] Hileman B. Chem. Eng. News , 1997 , 75 : 34
[ 6 ] Inoue S , Koinuma H , Tsuruta T. J . Polym. Sci . , Polym. Chem.Ed. , 1969 , 7 : 287
[ 7 ] 周忠清( Zhou Z Q) , 钱延龙(Qian Y L ) . 化学通报(Chemistry) , 1984 , (5) : 4 —11
[ 8 ] 吉媛媛(Ji Y Y) , 阴丽华(Yin L H) , 王常有(Wang C Y) .天然气化工(Natural Gas Chemical Industry) , 1991 , 16 (2) :52 —57
[ 9 ] Darensbourg D J , Holtcamp M W. Coo. Chem. Rev. , 1996 ,153 : 155 —174
[10] Backman E J . Science , 1999 , 283 : 946 —947
[11] 王东贤(Wang D X) , 元茂青(Yaun M Q) , 王心葵(Wang X K) . 化学进展( Progress in Chemistry) , 2002 , 14 (6) : 462 —468
[12] 沈玉梅( Shen Y M) , 施敏( Shi M) . 有机化学( Chinese Journal of Organic Chemistry) , 2003 , 23(1) : 22 —29
[13] 杨瑞娜(Yang R N) , 侯益民(Hou Y M) , 胡晓院(Hu X Y) ,金斗满(Jin D M) , 席振峰(Xi Z F) . 化学进展(Progress in Chemistry) , 2000 , 12(1) : 41 —50
[14] 施敏轶(Shi M Y) , 郝金库(Hao J K) . 天津化工( Tianjin Chemical Industry ) , 1997 , (4) : 2 —5
[15] 王建伟(Wang J W) , 钟顺和( Zhong S H) . 化学进展(Progress in Chemistry) , 1998 , 10(4) : 374 —380
[16] Inoue S. Prog. Polym. Sci . Jpn. , 1982 , 8 : 1
[17] Soga K, Imai E , Hattori I. , Polym. J . , 1981 , 13 : 407
[18] Kobayashi M, Inoue S , Tsuruta T. J . Polym. Sci . A: Polym.Chem. Ed. , 1973 , 11 : 2383
[19] Rokicki A. US 4 943 677 , 1990
[20] Kawacki H , Minami S , Armor J N , Rokicki A , Stei B K. US 4981 948 , 1991
[21] Chisholm M H , Navarro-Lcobet D , Zhou Z P , Macrommolecules ,2002 , 35 : 6494 —6504
[22] Ree M, Bae J Y, Jung J H , Shin T J . J . Polym. Sci . A: Polym.Chem. , 1999 , 37 : 1863 —1876
[23] Wang S J , Du L C , Zhao X S , Meng Y Z , Tjong S C. J . Appl .Polym. Sci . , 2002 , 85 : 2327 —2334
[24] Rokicki A , Kuran W J . Macromol . Sci . Rev. Macromol . Chem.Phys. , 1981 , 21 : 135
[25] Meng Y Z , Du L C , Tjong S C , Zhu Q , Hay A S. J . Polym.Sci . A: Polym. Chem. , 2002 , 40 : 3579 —3591
[26] Zhu Q , Meng Y Z , Tjong S C , Zhao X S , Chen Y Z. Polym.Int . , 2002 , 51 : 1079 —1085
[27] Zhu Q , Meng Y Z , Tjong S C , Zhang Y M, Wan W. Polym.Int . , 2003 , 52 : 799 —804
[28] Darensbourg D J , Wildesm J R , Yarbrough J C. Inorg. Chem. ,2002 , 41 : 973 —980
[29] Darensbourg D J , Wildesm J R , Yarbrough J C , Reibenspies J H.J . Am. Chem. Soc. , 2000 , 122 : 12487 —12496
[30] Kuran W, Pasynkiewicz S , Skupinska J . Macromol . Chem. ,1977 , 178 : 47
[31] Kuran W, Rokicki A , Wilinska E. Macromol . Chem. , 1979 ,180 : 2153
[32] Sǎrbu T , Beckman E J . Macromolecules , 1999 , 32 : 6904 —6912
[33] Darensbourg D J , Holtcamp M W. Macromolecules , 1995 , 28 :7577 —7579
[34] Darensbourg D J , Holtcamp M W, Struck G E. J . Am. Chem.Soc. , 1999 , 121 : 107 —116
[35] Darensbourg D J , Zimmer M S. Macromolecules , 1999 , 32 :2137 —2140
[36] Darensbourg D J , Niezgoda S A , Drapoer J D , Perbenspses J H.J . Am. Chem. Soc. , 1998 , 120 : 4690 —4698
[37] Darensbourg D J , Zimmer M S , Rainey Patrick , Larkins D C.Inorg. Chem. , 2000 , 39 : 1578 —1585
[38] Koning C , Wildeson J , Parton R , Plum B , Steeman P ,Darensbourg D J . Polymer , 2001 , 42 : 3995 —4004
[39] Dinger M B , Scott M J . Inorg. Chem. , 2001 , 40 : 1029 —1036
[40] Lukaszczyk J , Katarzyua J , Kuran W, Listos T. Macromol . Rapid Comm. , 2001 , 21 : 754 —757
[41] Huang S J . Encyclopedia of Polymer Science and Engineering (eds. Mark H F , Bikales N M, Overberger C G, Menges G) .New York : John Wiley , 1985. vol . 2 , p. 222
[42] Kopecek J , Vlbrich K. Prog. Polym. Sci . , 1983 , 9 : 1
[43] Inoue S , Koinuma H , Yokoo Y, Tsuruta T. Macromol . Chem. ,1971 , 143 : 97
[44] Nozaki K, Nakano K, Hiyama T. J . Am. Chem. Soc. , 1999 ,121 : 11008 —11009
[45] Nakano K, Nozaki K, Hiyama T. J . Am. Chem. Soc. , 2003 ,125 : 5501 —5510
[46] Darensbourg D J , Rainey P , Yarbrough J C. Inorg. Chem. ,2001 , 40 : 986
[47] Okamoto Y, Nakano T. Chem. Rev. , 1994 , 94 : 349
[48] Coates G W. Comprehensive Asymmetric Catalysis (eds. Jacobsen E N , Pftaltz A , Yamamoto H) . New York : Springer , 1999. vol .Ⅲ. chapter36
[49] Cheng M, Lobkovsky E B , Coates G W . J . Am Chem. Soc. ,1998 , 120 : 11018 —11019
[50] Cheng M, Darling N A , Lobkovsk E B , Coates G W. Chem.Comm. , 2000 : 2007 —2008
[51] Cheng M, Moore D R , Reckzek J J , Chamberlain B M,Lobkovsky E B , Coates G W. J . Am. Chem. Soc. , 2001 , 123 :8738 —8749
[52] Moore D R , Cheng M, Lobkovsky E B , Coates G W. Angew.Chem. Int . Ed. , 2002 , 41 : 2599 —2602
[53] Allen S D , Moore D R , Lobkovsky E B , Coates G W. J . Am.Chem. Soc. , 2002 , 124 : 14284 —14285
[54] Eberhardt D , Allmendinger M, Luinstra G A , Rieger B.Organometallics , 2003 , 22 : 211 —214
[55] Cheng M, Moore D R , Reckzek J J , Chamberlain B M,Lobkovsky E B , Coates GW. J . Am. Chem. Soc. , 2001 , 123 :8738 —8749
[56] Sita L R , Babcock J R , Xi R. J . Am. Chem. Soc. , 1996 , 118 :10912 —10913
[57] Liu Z , Torrent M, Morokuma K. Organometallics , 2002 , 21 :1056 —1071
[58] Super M S , Backman E J , Costello C , Berluche E.Macromolecules , 1997 , 30 : 368 —372
[59] Shi C , Huang I , Kilic S , Enick K M, Backman E J , et al . Am.Asso. Adv. Sci . , 1999 , 286 : 1540 —1543
[60] Darensbourg D J , Adams M J , Yarbrough J C. Inorg. Chem. ,2001 , 40 : 6543 —6544
[61] Darensbourg D J , Lews S J . Rodgors J L , Yarbrough J C. Inorg.Chem. , 2003 , 42 : 581 —589
[62] 周忠清(Zhou Z Q) . 河北化工(Hebei Chemical Engineering) ,1995 , (1) : 47 —50
[63] Chen L B. Macromol . Chem. , Macromol . Symp. , 1992 , 59 :75 —82
[64] Chen L B , Chen H S , Lin J J . Macromol . Sci .-Chem. , 1987 ,A24 (3/4) : 253 —260
[65] 陈立班(Chen L B) , 林芳灵(Lin F L) , 林欣欣(Lin X X) ,陈海生( Chen H S) . 广州化工( Guangzhou Chemical Industry) , 1988 , (2) : 29 —32
[66] 陈立班(Chen L B) , 林欣欣(Lin X X) , 陈海生(Chen H S) ,林芳灵(Lin F L) . 应用化学(Chinese Journal of Applied Chemistry) , 1988 , 5 : 7 —11
[67] 杨淑英(Yang S Y) , 陈立班(Chen L B) . 催化学报(Chinese Journal of Catalysis) , 1992 , 13(2) : 156 —159
[68] 张南燕(Zhang N Y) , 杨淑英( Yang S Y) , 余爱芳( Yu A F) , 何树杰( He S J ) , 陈立班( Chen L B) . 广州化学(Guangzhou Chemistry) , 2000 , 25(4) : 1 —4
[69] 张南燕(Zhang N Y) , 陈立班(Chen L B) , 杨淑英( Yang S Y) , 余爱芳(Yu A F) , 何树杰(He SJ) . 高分子学报(Acta Polymerica Sinica) , 2000 , (6) : 741 —745
[70] 张敏(Zhang M) , 陈立班(Chen L B) , 秦刚(Qin G) , 李卓美(Li Z M) . 高分子学报(Acta Polymerica Sinica) , 2001 ,(3) : 422 —424
[71] Kuran W, Listors T. Macromol . Chem. Phys. , 1994 , 195 :977 —983
[72] Kruper W J , Della D V. J . Org. Chem. , 1995 , 60 : 725 —731
[73] Mang S , Cooper A I , Colclough M E , Chauhan N , Holmes A B.Macromolecules , 2000 , 33 : 303 —308
[74] Seamp L M, Mang S , Holmes A B , et al . Chem. Comm. , 2001 ,2502 —2503
[75] Darensbourg D J , Yarbrough J C. J . Am. Chem. Soc. , 2002 ,124 : 6335 —6342
[76] Hansen K B , Lighton J C , Jacobsen E N. J . Am. Chem. Soc. ,1996 , 118 : 10924
[77] Jacobsen E N. Acc. Chem. Res. , 2000 , 33 : 421
[78] Nozaki K, Nakano K, Hiyama T. Macromolecules , 2001 , 34 :6325 —6332
[79] Cheng M, Darling N A , Lobkovsky E B , Coates G W. Chem.Comm. , 2000 , 2007 —2008
[80] Darensbourg D J , Yarbrough J C , Ortiz C , Fang C C. J . Am.Chem. Soc. , 2003 , 125 : 7586 —7591
[81] Chen X, Shen Z , Zhang Y. Macromolecules , 1991 , 24 : 5305 —5308
[82] 郭锦棠(Guo J T) , 孙经武(Sun J W) , 张颖萍(Zhang Y P) ,高峰(Gao F) , 王新英(Wang X Y) . 高分子材料科学与工程( Polymer Materials Science & Engineering) , 1999 , 15 (3) :57 —60
[83] Guo J T , Wang X Y, Xu Y S , Sun J W. J . Appl . Sci . , 2003 ,87 : 2356 —2359
[84] Tan C S , Hsu T J . Macromolecules , 1997 , 30 : 3147 —3150
[85] Hsu T J , Tan C S. Polymer , 2001 , 42 : 5143 —5150
[86] Hsu T J , Tan C S. Polymer , 2002 , 43 : 4535 —4543
[87] Liu B Y, Zhao X J , Zhao D Q , et al . 6th Pacific Polymer Conference. Guangzhou , Preprint , 1999. 67
[88] Liu B Y, Zhao X J , Wang F S. J . Polym. Sci . , Part A: Polym.Chem. , 2001 , 39 : 2751 —2754
[89] Liu B Y, Zhao X J , Wang F S. Polymer , 2003 , 44 : 1803 —1808
[90] Racanelli P , Porri L. Eur. Polym. J . , 1994 , 6 : 751
[91] Chen X, Shen Z , Zhang Y. Macromolecules , 1991 , 24 : 5305 —5308
[92] Shen Z Q , Chen X H , Zhang Y F. Macromol . Chem. Phys. ,1994 , 195 : 2003
[93] Rokicki A , Kuran W J . Macromol . Sci . Rev. Macromol .Chem. , 1981 , C21 : 135
[94] Koinuma H , Hirai H. Macromol . Chem. , 1977 , 178 : 1283 —1289
[95] Takeda N , Inoue S. Macromol . Chem. , 1978 , 179 : 1377 —1382
[96] Aida T , Inoue S. J . Am. Chem. Soc. , 1983 , 105 : 1304 —1311
[97] Aida T , Inoue S. Macromolecules , 1982 , 15 : 682 —684
[98] Aida T , Inoue S. Macromolecules , 1986 , 19 : 8 —13
[99] Jung J H , Ree M, Chang T J . J . Polym. Sci . Part A: Polym.Chem. , 1999 , 37 : 3329 —3336
[100] Inoue S. J . Polym. Sci . Part A , 2002 , 38 : 2861 —2871
[101] Sarbu T , Styranel T , Beckman E J . Nature , 2000 , 405 : 165 —168
[102] Darensbourg D J , Wildeson J R , Lews S J , Yarbrough J C. J .Am. Chem. Soc. , 2002 , 124 : 7075 —7083
[103] Preprints of China-Japan Bilateral Symposium on Effective Utilization of Carbon Resources. Guangzhou , China , 1991. 26
[104] 陈仙海(Chen X H) , 张一峰( Zhang Y F) , 沈之荃(Shen Z Q) . 精细石油化工(Fine Petroleum Chemical Industry) , 1991 ,(5) : 42 —44
[1] Jiaye Li, Peng Zhang, Yuan Pan. Single-Atom Catalysts for Electrocatalytic Carbon Dioxide Reduction at High Current Densities [J]. Progress in Chemistry, 2023, 35(4): 643-654.
[2] Yuewen Shao, Qingyang Li, Xinyi Dong, Mengjiao Fan, Lijun Zhang, Xun Hu. Heterogeneous Bifunctional Catalysts for Catalyzing Conversion of Levulinic Acid to γ-Valerolactone [J]. Progress in Chemistry, 2023, 35(4): 593-605.
[3] Chunyi Ye, Yang Yang, Xuexian Wu, Ping Ding, Jingli Luo, Xianzhu Fu. Preparation and Application of Palladium-Copper Nano Electrocatalysts [J]. Progress in Chemistry, 2022, 34(9): 1896-1910.
[4] Bin Jia, Xiaolei Liu, Zhiming Liu. Selective Catalytic Reduction of NOx by Hydrogen over Noble Metal Catalysts [J]. Progress in Chemistry, 2022, 34(8): 1678-1687.
[5] Deshan Zhang, Chenho Tung, Lizhu Wu. Artificial Photosynthesis [J]. Progress in Chemistry, 2022, 34(7): 1590-1599.
[6] Mingjue Zhang, Changpo Fan, Long Wang, Xuejing Wu, Yu Zhou, Jun Wang. Catalytic Reaction Mechanism for Hydroxylation of Benzene to Phenol with H2O2/O2 as Oxidants [J]. Progress in Chemistry, 2022, 34(5): 1026-1041.
[7] Shiying Yang, Danyang Fan, Xiaojuan Bao, Peiyao Fu. Modification Mechanism of Zero-Valent Aluminum by Carbon Materials [J]. Progress in Chemistry, 2022, 34(5): 1203-1217.
[8] Fengshou Yu, Jiayu Zhan, Lu-Hua Zhang. The progress on Electrochemical CO2-to-Formate Conversion by p-Block Metal Based Catalysts [J]. Progress in Chemistry, 2022, 34(4): 983-991.
[9] Shujin Shen, Cheng Han, Bing Wang, Yingde Wang. Transition Metal Single-Atom Electrocatalysts for CO2 Reduction to CO [J]. Progress in Chemistry, 2022, 34(3): 533-546.
[10] Bolin Zhang, Shengyang Zhang, Shengen Zhang. The Use of Rare Earths in Catalysts for Selective Catalytic Reduction of NOx [J]. Progress in Chemistry, 2022, 34(2): 301-318.
[11] Wu Qiaomei, Yang Qiyue, Zeng Xianhai, Deng Jiahui, Zhang Liangqing, Qiu Jiarong. Catalytic Conversion of Cellulose-Based Biomass to Diols [J]. Progress in Chemistry, 2022, 34(10): 2173-2189.
[12] Bai Wenji, Shi Yubing, Mu Weihua, Li Jiangping, Yu Jiawei. Computational Study on Cs2CO3-Assisted Palladium-Catalyzed X—H(X=C,O,N, B) Functionalization Reactions [J]. Progress in Chemistry, 2022, 34(10): 2283-2301.
[13] Yang Linyan, Guo Yupeng, Li Zhengjia, Cen Jie, Yao Nan, Li Xiaonian. Modulation of Surface and Interface Properties of Cobalt-Based Fischer-Tropsch Synthesis Catalyst [J]. Progress in Chemistry, 2022, 34(10): 2254-2266.
[14] Yuan Su, Keming Ji, Jiayao Xun, Liang Zhao, Kan Zhang, Ping Liu. Catalysts for Catalytic Oxidation of Formaldehyde and Reaction Mechanism [J]. Progress in Chemistry, 2021, 33(9): 1560-1570.
[15] Xuechuan Wang, Yansong Wang, Qingxin Han, Xiaolong Sun. Small-Molecular Organic Fluorescent Probes for Formaldehyde Recognition and Applications [J]. Progress in Chemistry, 2021, 33(9): 1496-1510.