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Progress in Chemistry 2005, Vol. 17 Issue (04): 651-659 Previous Articles   Next Articles

• Review •

Review of Catalytic Dehydrogenation of Isobutene

Li Li;Yan Zifeng**   

  1. Stake Key Laboratory of Heavy Oil Processing, CNPC Key Laboratory of Catalysis, China University of Petroleum,Dongying 257061,China
  • Received: Revised: Online: Published:
  • Contact: Yan Zifeng
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Recent progress of the catalysts, reaction routes and mechanism of isobutane dehydrogenation is reviewed. The key for isobutane dehydrogenation is to synthesize non-noble mental catalysts. Furthermore, the influence of supports and additives on isobutane dehydrogenation is summed up in detail, especially acid-base supports and additives and pore structure of supports, which indicates that weak acidic sites are apt to isobutane dehydrogenation. Smaller pore structure of catalysts can improve selectivity of isobulane. Besides, the study of coke over catalysts reveals that weak acidic sites of supports, dispersion of active sites and basic sites of additives favors improved action of coke.
Key words: isobutene dehydrogenation, catalysts, reaction mechanism, coke

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[ 1 ] 钱伯章(Qian B Z) . 天然气化工(Natural Gas Chemical Industry) , 1994 , 19 : 43 —52
[ 2 ] 蔡俊修( Cai J X) , 陈笃慧( Chen D H) . 精细石油化工(Specialty Petrochemicals) , 1994 , (2) : 48 —52
[ 3 ] 蔡俊修(Cai J X) . 精细石油化工(Specialty Petrochemicals) ,1994 , (1) : 12 —15
[ 4 ] 焦宁宁(Jiao N N) , 郝爱(Hao A) . 石化技术( Petrochemical Technology) , 1995 , 2 (3) : 194 —199
[ 5 ] 焦宁宁(Jiao N N) , 王建明(Wang J M) . 石油化工技术经济(Techno-Economics in Petrochemicals) , 1996 , 12 (3) : 33 —37
[ 6 ] 李亚军(Li Y J ) . 兰化科技( Petrochemical Technology &Application) , 1994 , 12 (2) : 134 —137
[ 7 ] 阎子峰(Yan Z F) . 纳米催化技术(Nanocatalysis Technology) .北京(Beijing) : 化学工业出版社(Chemical Industry Press) ,2003
[ 8 ] Liebmann L S , Schmidt L D. Appl . Catal . A: General , 1999 ,179 : 93 —106
[ 9 ] Bharadwaj S S , Schmidt L D. J . Catal . , 1995 , 155 : 403 —413
[10] Shimada H , Akazawa T , Ikenaga N , et al . Appl . Catal . A:General , 1998 , 168 : 243 —250
[11] Cortright R D , Hill J M, Dumesic J A. Catal . Today , 2000 , 55(3) : 213 —223
[12] Hill J M, Cortright R D , Dumesic J A. Appl . Catal . A:General , 1998 , 168 : 9 —21
[13] 林励吾(Lin L W) , 杨维慎(Yang W S) , 贾继飞(Jia J F) , et al . 中国科学(B 辑) (Science in China (Series B) ) , 1999 , 29(2) : 109 —117
[14] Grabowski R , Grzybowska B , Sloczynski J , et al . Appl . Catal .A: General , 1996 , 144 : 335 —341
[15] Iannazzo V , Neri G, Galvagno S , et al . Appl . Catal . A:General , 2003 , 246 : 49 —68
[16] Moriceau P , Grzybowska B , Barbaux Y, et al . Appl . Catal . A:General , 1998 , 168 : 269 —277 ; 2000 , 199 (1) : 73 —82
[17] Vislovskiy V P , Shamilov N T , Sardarly A M, et al . J . Chem.Eng. , 2003 , 95(1/3) : 37 —45
[18] Cauzzi D , Deltratti M, Predieri G, et al . Appl . Catal . A:General , 1999 , 182 : 125 —135
[19] Z?avoianu R , Dias C R , Portela M F. Catal . Comm. , 2001 , 2(1) : 37 —42
[20] Predieri G, Cauzzi D , Deltratti M, et al . Appl . Catal . A:General , 1999 , 182 : 125 —135
[21] Zhang Y J , Rodriguez-Ramos I , Guerrero-Ruiz A. Catal . Today ,2000 , 61(1/4) : 377 —382
[22] Al-Zahrani S M, Elbashir N O , Abasaeed A E , et al . Ind. Eng.Chem. Res. , 2001 , 40 : 781 —784
[23] Karamullaoglu G, Onen S , Dogu T. Chem. Eng. Pro. , 2002 , 41(4) : 337 —347
[24] 陶跃武(Tao Y W) , 钟顺和(Zhong S H) . 应用化学(Chinese J . Appl . Chem. ) , 2001 , 18(1) : 16 —20
[25] Takita Y, Kurosaki K, Mizuhara Y, et al . Chem. Lett . , 1993 ,335 —347
[26] Takita Y, Sano K, Kurosaki K, et al . Appl . Catal . A: General ,1998 , 167 : 49 —56
[27] Takita Y, Sano K, Muraya K T , et al . Appl . Catal . A: General ,1998 , 170 : 23 —33
[28] Al-Zahrani S M, Elbashir N O , Abasaeed A E , et al . Catal .Lett . , 2000 , 69 : 65 —70
[29] Sulikowski B , Olejniczak Z , Wloch E , et al . Appl . Catal . A:General , 2002 , 232 : 189 —202   
[30] 李工(Li G) , 张春雷(Zhang C L) , 吴通好(Wu T H) . 石油化工(Petrochemical Technology) , 1999 , 28(5) : 286 —289
[31] Jalowiecki-Duhamel L , Monnier A , Barbaux Y, et al . Catal .Today , 1996 , 32 : 237 —241
[32] Finke R G. Polyoxometalates : from Platonic Solids to Antiretroviral Activity ( eds. Pope M T , Müller A) . Dordrecht : Kluwer Academic , 1993. 267
[33] Lyon D K, Miller W K, Novet T , et al . J . Am. Chem. Soc. ,1991 , 113 : 7209 —7221
[34] Cavani F , Comuzzi C , Dolcetti G, et al . J . Catal . , 1996 , 160 :317 —321
[35] 张伟德(Zhang W D) , 洪碧凤(Hong B F) , 古萍英( Gu P Y)等. 应用化学(Chinese J . Appl . Chem. ) , 1998 , 3 : 76 —78
[36] Bi Y L , Zhen K J , Valenzuel R X, et al . Catal . Today , 2000 ,61(1/4) : 369 —375
[37] Hill J M, Cortright R D , Dumesic J A. Appl . Catal . A:General , 1998 , 168 : 9 —21
[38] de Rossi S , Ferraris G, Freminotti S , et al . Appl . Catal . A:General , 1993 , 106 : 125 —141
[39] Huff M, Schmidt L D. J . Catal . , 1995 , 155 : 82 —94
[40] Elbashir N O , Al-Zahrani S M, Abasaeed A E , et al . Chem.Eng. Proc. , 2003 , 42 : 817 —823
[41] 丁彦(Ding Y) , 潘霞(Pan X) , 薛锦珍(Xun J Z) 等. 分子催化(J . Mol . Catal . ) , 1999 , 13(5) : 373 —377
[42] 马红超(Ma H C) , 刘子玉(Liu Z Y) , 王振旅(Wang Z L) 等.高等学校化学学报(Chem. J . Chinese Universities) , 2002 , 23(5) : 857 —860
[43] 王心葵(Wang X K) , 解红娟(Xie H J ) , 张亮玫(Zhang L M)等. 天然气化工(Natural Gas Chemical Industry) , 1995 , 20(3) : 22 —24
[44] Airaksinen S M K, Harlin M E , Krause A O I. Ind. Eng. Chem.Res. , 2002 , 41 : 5619 —5626
[45] 王桂茹(Wang G R) . 催化剂与催化作用( Catalysts and Catalysis) . 大连理工出版社(Dalian University of Technology Press) , 2002
[46] McVicker G B , Kramer G M, Ziemiak J J . J . Catal . , 1983 , 83 :286 —291
[47] Kramer G M, McVicker G B , Ziemiak J J . J . Catal . , 1985 , 92 :355 —358
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