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Progress in Chemistry 2005, Vol. 17 Issue (03): 389-398 Previous Articles   Next Articles

• Review •

Progress in Water-Gas-Shift Catalysts

Liu Quansheng**;Zhang Qiancheng;Ma Wenping;He Runxia;Kou Lijie;Mou Zhanjun   

  1. Institute of Chemical Engineering, Inner Mongolia University of Technology,Hohhot 010062,China
  • Received: Revised: Online: Published:
  • Contact: Liu Quansheng
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The reforming of hydrocarbon with water vapor and the water-gas-shift reaction (WGSR) are the traditional and economic technologies for the production of hydrogen. Three classes of WGSR catalysts, e.g. Fe2 O3 -Cr2O3, CuO-ZnO-Al2 O3 and Co-MoO3-Al203, have been commercialized in the world after continuing efforts during the past 80 years. Recent years, the WGSR catalysts have drawn renewed attention due to its appearing/applying in the fuel cell (FC) technology, which is a fast developing topic today. This paper reviews comprehensively the traditional WGSR catalysts and recent progress of the WGSR catalysts used in the FC. It is recommended that the research direction of the WGSR catalysts for the FC should be directed to the bi-functional noble metal/support catalysts. The types of noble metal and support, preparation procedures and conditions affect significantly the catalyst particle size and distribution, bulk texture, surface property and catalyst activity. This paper also points that the current bi-functional noble metal/support WGSR catalysts for the FC cannot meet application requirements now even though they have more advantages than traditional WGSR catalysts used in ammonia plants.
Key words: water-gas-shift catalysts, fuel cells, pure hydrogen production, noble metal/support catalysts, rare earth oxides

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Progress in Water-Gas-Shift Catalysts