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Progress in Chemistry 2005, Vol. 17 Issue (02): 299-309 Previous Articles   Next Articles

• Review •

The Synthesis of Polydiaminonaphthalene and Its Highly Reactive 　 Adsorption for Heavy Metal Ions

Huang Meirong   Li Xingui**   Li Shengxian   

  1. ( Institute of Materials Chemistry , Laboratory of Concrete Materials Research , College of Materials Science & Engineering , Tongji University , Shanghai 200092 , China)
  • Received: Revised: Online: Published:
  • Contact: Li Xingui E-mail:lixingui @tongji. edu. cn
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Polydiaminonaphthalene is a new type of conducting polymer following polyaniline and polypyrrole , which possess new multiple functionalities owing to the amine and secondary amino groups in the polymer chain. The chemically and electrochemically oxidative synthesis of 1 ,8-,1 ,5-and 2 ,3- diaminonaphthalene , as well as their ad2 sorptions for heavy metal ions via complexation or redox , are systematically reviewed based on our recent research and the latest literature. The characteristics of the two synthetic methods are compared in detail . It is pointed out that polydiami2 nonaphthalene2modified electrodes sensitive to heavy metal ions ,such as Ag+ ,Pb2+ ,Hg2+ ,Cu2+ ,VO2+ ,could be sim2 ply obtained by electrochemically oxidative polymerization. The polydiaminonaphthalene particles having a prodigious re2 duction adsorption capacity for Ag+ could be prepared with a high yield by chemically oxidative polymerization. The polydiaminonaphthalenes have shown a great potential development in analysis and detection for trace metallic ions , as well as the recovery of precious metal ions and removal of heavy metal ions from water effluents.

Key words: polydiaminonaphthalene, chemically oxidative polymerization, electrochemically oxidative polymeriza tion, heavy metal ions, adsorption

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