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Progress in Chemistry 2005, Vol. 17 Issue (02): 225-232 Previous Articles   Next Articles

• Review •

Progress in Deactivation of Titanium Oxide Photocatalyst

Tang Yuchao1,2**　Hu Chun2 　Wang Yizhong2 　Zhang Haiping1 　Huang Xianhuai1   

  1. (1. Department of Environmental Engineering , Anhui Institute of Architecture and Industry , Hefei 230022 , China ; 2. Research Center for Eco2Environmental Sciences , Chinese Academy of Sciences , Beijing 100085 , China)
  • Received: Revised: Online: Published:
  • Contact: Tang Yuchao E-mail:ahfxtyc @sina. com
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Titanium oxide photocatalysis is a potential technology for environmental purification , but catalysts deactivation occurred during photocatalytic reaction. In this paper , recent advances of deactivation for the titanium oxide photocatalyst in environmental pollution control processes have been summarized. The mechanisms of deactivation in gas2 solid and liquid2solid reaction are discussed in detail . The effects of water on photoactivity for titanium oxide gas2solid reaction are presented. Adsorption of some non2degraded compounds on surface of TiO2 and structures of special surface of TiO2 altered by some intermediates are the most reasons for deactivation processes. Electrons and holes or the hydroxyl radical captured will give the lower apparent photoactivity of the reaction. Factors which have different effects on deactivation process are discussed also.

Key words: multiscale, complexity, nonlinear

CLC Number: 

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