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Progress in Chemistry 2005, Vol. 17 Issue (02): 209-216 Previous Articles   Next Articles

• Special issues •

The Development in Hydroformylation of Higher Olefin in LiquidPLiquid Biphase Systems

feng Cuilan Wang Yanhua Jin Zilin**   

  1. (State Key Laboratory of Fine Chemicals , Dalian University of Technology , Dalian 116012 , China)
  • Received: Revised: Online: Published:
  • Contact: Jin Zilin E-mail:hpzuo @mail. dlptt. ln. cn
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The development in hydroformylation of higher olefins in liquidP liquid biphase systems is reviewed , par2 tially based on the authors’research results in recent years. The classical aqueousPorganic biphase system is unsuitable for hydroformylation of higher olefins. In order to solve this problem , six kinds of improved methods including thermoreg2 ulated phase2transfer catalysis are introduced in detail . In addition , the hydroformylation of higher olefins in nonaqueous liquidP liquid biphase systems , such as fluorous biphasic system , non2aqueous ionic liquid and supercritical fluid is also introduced. Meanwhile , the possibilities of commercial applications of each system have been discussed.

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