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Progress in Chemistry 2005, Vol. 17 Issue (01): 130-136 Previous Articles   Next Articles

• Review •

Recent Advances of the Perfluoroalkylsulfonate and Bis-(perfluoroalkylsulfonyl) imide Complexes in Heterogeneous Catalysis

Ding Junjie  Ding Xiaoqin*   Zhao Lifeng  Chen Jisheng   

  1. (Beijing Institute of Pharmaceutial Chemistry , Beijing 102205 , China)
  • Received: Revised: Online: Published:
  • Contact: Ding Xiaoqin E-mail:dingxq @cetin. net. cn
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Conventional Lewis acid catalysts are now of great challenge especially in relation to today' s environmen-tal concerns. The use of perfluoroalkylsulfonate and bis(perfluoroalkylsulfonyl)imide complexes as homogeneous and high-efficient Lewis acid catalysts in organic synthesis has been the subject of numerous publications. For the simplifications of separation and isolation, the immobilized homogeneous catalysts have been made great progress. Recent advances of the perfluoroalkylsulfonate and bis(perfluoroalkylsulfonyl)imide complexes in heterogeneous catalysis and its preparation and activity when immobilized by organic supports, inorganic supports and ion liquids are reviewed, and the prospect for the heterogeneous catalysts is also proposed.

Key words: perfluoroalkylsulfonate complexes, bis (perfluoroalkylsulfonyl)imide complexes, Lewis acid, hetero-geneous catalysis

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