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Progress in Chemistry 2004, Vol. 16 Issue (04): 603- Previous Articles   Next Articles

• Review •

Advances of Rhodium-Catalyzed Enantioselective Hydrogenation of Functional Olefins--The Thriving of Monodentate Phosphorous Ligands

Zeng Qingli1,2**;Mi Aiqiao3;Jiang Yaozhong3   

  1. (1.Department of Pharmacy, Sichuan University, Chengdu 610041, China; 2.Institute of New Medicine, Di'ao Group, Chengdu 610041, China; 3.Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu 610041, China)

  • Received: Revised: Online: Published:
  • Contact: Zeng Qingle
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The whole historical progress in rhodium-catalyzed enantioselective hydrogenation of fuctional olefins is reviewed briefly. Specially, the recently thriving of monodentate phosphorous ligands is discussed in detail. A construc-tive prospect about the research is given.
Key words: asymmetric catalysis, hydrogenation, rhodium, functional olefins, phosphorous ligands, amino ac-ids, monodentate ligands

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