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Progress in Chemistry 2004, Vol. 16 Issue (04): 574- Previous Articles   Next Articles

• Review •

(Dynamic) Kinetic Resolution Reactions of Racemes Catalyzed by Lewis Acid and Base Catalysts

Zhang Zhanjin1,2;Mao Jincheng2;Wan Boshun2;Chen Huilin2   

  1. (1.College of Chemistry and Food Science, Bohai University, Jinzhou 121000; 2.Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023)
  • Received: Revised: Online: Published:
  • Contact: Zhang Zhanjin
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The (dynamic) kinetic resolution of raceme is one of the important ways in the synthesis of chiral com-pounds. The reaction can be realized by enzymatic or non-enzymatic catalysis or by combination of two methods. The cat-alytic systems of Lewis acid and base are useful ways in the non-enzymatic catalysis. They were widely used to different kinds of (dynamic) kinetic resolution reactions. At present, mighty advances have been made in the field. Recent progress in the applications of non-enzymatic system about Lewis acid and base to (dynamic)kinetic resolution reactions of racemes is reviewed.
Key words: Lewis acid and base, raceme, (dynamic)kinetic resolution, non-enzymatic catalysis

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