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Progress in Chemistry 2004, Vol. 16 Issue (04): 500- Previous Articles   Next Articles

• Review •

Hierarchical Self-Assembly of Inorganic Nanoparticles Mediated by Organic Macromolecules

Yuan Jianjun;Zhai Jin;Jiang Lei**   

  1. (The Center of Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences,Beijing 100080, China)
  • Received: Revised: Online: Published:
  • Contact: Jiang Lei
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The hierarchical self-assembly of inorganic nanoparticles mediated by the tailed organic macromolecules has been reviewed. The organic macromolecules used for the mediators include the synthetic polymers and the biopoly-mers. Up to now, the polymers with hydrogen-bond recognition functionality, polyelectrolytes, block copolymers and den-drimers have been developed as synthetic polymers for the assembly of the inorganic nanoparticles. At the same time, DNA, amylose and proteins also present the impressive ability for the ordered aggregation of inorganic nanoparticles. It is necessary for the hierarchical assembly of inorganic nanoparticles to modify them to afford their surfaces tailored function-ality , for example hydrogen-bond recognition groups, positive charges, negative charges, and so on, which can recognize with the organic mediators. This research field is very essential for the construction of advanced functional materials and biomimetic materials.
Key words: self-assembly, inorganic nanoparticles, macromolecules, hierarchical order

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