中文
Announcement
More
Progress in Chemistry 2004, Vol. 16 Issue (02): 256- Previous Articles   Next Articles

• Review •

R&D of Precipitated Iron Catalysts in Fischer-Tropsch Synthesis

Wu Baoshan;Tian Lei;Bai Liang;Zhang Zhixin;Xiang Hongwei**;Li Yongwang   

  1. (The State Key Laboratory of Coal Conversion, Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China)
  • Received: Revised: Online: Published:
  • Contact: Xiang Hongwei
PDF ( 1523 ) Cited
Export

EndNote

Ris

BibTeX

Fischer-Tropsch synthesis is one of the most important processes in coal conversion to liquid fuels via syngas. The choice of slurry bubble reactor and iron-based catalysts with low cost and high efficiency is a practicable and efficient route for the conversion of coal-derived syngas with low H2/CO ratio. In this paper, the development of F-T syn-thesis process is reviewed. The preparation chemistry, the shaping methods, the active phase composition and the pretreatment conditions of precipitated iron catalysts for the use in slurry reactor and their effects on F-T synthesis performances are introduced in detail. The trend and direction of R&D for this type catalyst are also presented and prospected.

CLC Number: 

[ 1 ] Fischer F. Brennst . Chem. , 1923 , 4 : 276 —285
[ 2 ] Dry M E. Catal . Rev. Sci . Eng. , 1981 , 23 (1&2) : 265 —278
[ 3 ] 吕启东(Lü Q D) . 中国化工信息( Information of Chinese Chemical Engineering) , 2001 , 14 : 3 —9
[ 4 ] 相宏伟(Xiang H W) , 唐宏青(Tang H Q) , 李永旺(Li Y W) .燃料化学学报(Journal of Fuel Chemistry and Technology) ,2001 , 29 (4) : 289 —298
[ 5 ] Dry M E. Catal . Today , 2002 , 71 : 227 —241
[ 6 ] SASOL. Innovation or progress , 1999 , 46 —67
[ 7 ] SASOL. The Slurry phase distillate process , 1999 , 1 —12
[ 8 ] Knott D. OGJ , 1997 , 95 (25) : 16 —21
[ 9 ] Sie S T. Rev. Chem. Eng. , 1998 , 14 (2) : 109 —157
[10] Sie S T, Van Wechem H M H. Catal . Today , 1991 , 8 : 371 —394
[11] Wender I. Fuel Process. Tech. , 1996 , 48 : 189 —297
[12] Gerard P. Catal . Rev. Sci . Eng. , 1999 , 41 (3P4) : 255 —318
[13] Kolbel H , Ralek M. Catal . Rev. Sci . Eng. , 1980 , 21 : 225 —274
[14] Schulz H. Appl . Catal . A , 1999 , 186 : 3 —12
[15] Jager B. Stud. Surf . Sci . Catal . , 1997 , 107 : 219 —228
[16] Van Berge P J , Everson R C. Stud. Surf . Sci . Catal . , 1997 ,107 : 207 —212
[17] Senden M M G. Stud. Surf . Sci . Catal . , 1998 , 119 : 961 —966
[18] Dry M E. Appl . Catal . A , 1999 , 189 : 185 —190
[19] Espinoza R L , Steynberg A P , Jager B , et al . Appl . Catal . A ,1999 , 186 : 13 —26
[20] Steynberg A P , Espinoza R L , Jager B , et al . Appl . Catal . A ,1999 , 186 : 41 —54
[21] Davis B T. Catal . Today , 2003 , 84 : 83 —98
[22] Schulz H , van Steen E , Claeys M. Stud. Surf . Sci . Catal . ,1994 , 81 : 455 —460
[23] Kolbel H , Ackermann P. Chem. Eng. Tech. , 1956 , 28 : 381 —389
[24] Eisenberg B , Fiato R A , Mauldin C H , et al . Stud. Surf . Sci .Catal . , 1998 , 119 : 943 —950
[25] Duvenhage D , Coville N , Espinoza R. Stud. Surf . Sci . Catal . ,1994 , 88 : 3501 —3513
[26] Jager B. Stud. Surf . Sci . Catal . , 1998 , 119 : 25 —37
[27] Jager B R , Espinoza R. Catal . Today , 1995 , 23 : 17 —28
[28] 张碧江主编( ed. Zhang B J ) . 煤基合成液体燃料(Coal Based Synfuel) . 山西科技出版社(Shanxi Science and Technology Press) , 1993 , 326 —373
[29] Rao V U S , Stiegel GJ , Cinquegrane GJ . Fuel Process Technol . , 1992 , 30 (1) : 83 —107
[30] 相宏伟(Xiang H W) , 钟炳(Zhong B) . 化学进展(Progress in Chemistry) , 1999 , 11 (4) : 385 —393
[31] Hoogengdorn J C , Salomon J M. Brit . Chem. Eng. , 1957 , 308 :368 —418
[32] Steynberg A P , Espinoza R L , Jager B , et al . Appl . Catal . A ,1999 , 186 : 41 —54
[33] Bukur D B , Lang X S. Ind. Eng. Chem. Res. , 1999 , 38 :3270 —3275
[34] Lox E S , Marin G B. Appl . Catal . , 1988 , 40 (1P2) : 197 —218
[35] Ji Y, Xiang H , Li Y W. Appl . Catal . A , 2001 , 214 : 77 —86
[36] Bai L , Xiang H , Li Y W. Fuel , 2002 , 81 : 1577 —1581
[37] Bukur D B , Lang X, Mukesh D , et al . Ind. Eng. Chem. Res. ,1990 , 29 :1588 —1599
[38] Bukur D B , Mukesh D , Patel S A. Ind. Eng. Chem. Res. ,1990 , 29 : 194 —204
[39] Raje A P , O′Brien R J , Davis B H. J . Catal . , 1998 , 180 :36 —43
[40] Milburn D R , Chary K V R , Davis B H. Appl . Catal . A , 1996 ,144 : 121 —132
[41] Wang D , Cheng X. Appl . Catal . A , 1991 , 77 : 109 —122
[42] Li S , Krishnamoorthy S , Li A , et al . J . Catal . , 2002 , 206 :202 —217
[43] Bukur D B , Sivaraj C. Appl . Catal . A , 2002 , 231 : 201 —214
[44] Kolbel H , Ralek R. Catal . Rev. Sci . Eng. , 1980 , 21 : 225 —274
[45] Bukur D B , Nowichi L , Lang X S. Chem. Eng. Sci . , 1994 , 49 :4615 —4625
[46] Bukur D B , Patel S A , Lang X. Appl . Catal . A , 1990 , 61 :329 —349
[47] 张志新(Zhang Z X) , 周敬来(Zhou J L) , 林恒生(Ling H S) .天然气化工(Natural Gas Chemical Industry) , 1991 ,16 (6) :6 —10
[48] 马文平(Ma W P) , 赵玉龙(Zhao Y L) , 李永旺(Li Y W) . 天然气化工(Natural Gas Chemical Industry) , 1998 , 23 (3) : 1 —6
[49] 马文平(Ma W P) , 赵玉龙(Zhao Y L) , 李永旺(Li Y W) . 燃料化学学报(Journal of Fuel Chemistry and Technology) , 1999 ,27 (1) : 41 —44
[50] 吕毅军(Lu YJ ) , 张志新(Zhang Z X) , 周敬来(Zhou J L) . 天然气化工(Natural Gas Chemical Industry) , 1997 , 22 ( 4) :18 —23
[51] Lu Y, Zhang Z, Zhou J . J . Natural Gas. Chem. , 1999 , 8 (1) :82 —88
[52] Li Y W, Xiang H , Sun Y, et al . The 7th China-Japan Symposium on Coal and C1 Chemistry Proceedings , Haikou , China , 1 —8
[53] Wang Y, Li Y W, Zhao Y, et al . J . Fuel Chem. Tech. , 1999 ,27 (3) : 193 —202
[54] Wang Y, Xu Y, Xiang H , et al . Ind. Eng. Chem. Res. , 2001 ,40 : 4324 —4332
[55] Burkur D B , Lang X, Rosiin J A , et al . Ind. Eng. Chem.Res. , 1989 , 28 : 1130 —1140
[56] Guczi L. Catal . Rev. Sci . Eng. , 1981 , 23 (3) : 329 —376
[57] Diffenbach R A , Fauth D J . J . Catal . , 1986 , 100 : 466 —476
[58] Motjope T R , Dlamini H T, Hearne G R , et al . Catal . Today ,2002 , 71 : 335 —341
[59] Datye A K. Appl . Catal . A , 1995 , 133 : 335 —350
[60] Pham H N , Datye A K. Catal . Today , 2000 , 58 : 233 —240
[61] Sault A G, Datye A K. J . Catal . , 1993 , 140 (1) : 136 —149
[62] Jin Y, Datye A K. J . Catal . , 2000 , 196 : 8 —17
[63] Zhao R , Goodwin J G Jr , Jothimurugesan K, et al . Ind. Eng.Chem. Res. , 2001 , 40 : 1065 —1075
[64] Jothimurugesan K, Goodwin J G, Gangwal S K, et al . Catal . Today , 2000 , 58 : 335 —344
[65] Zhao R , Sudsakorn K, Goodwin J G, et al . Catal . Today , 2002 ,71 : 319 —326
[66] Baltrus J P , Diehl J R , McDonald M A , et al . Appl . Catal . ,1989 , 48 (1) : 199 —213
[67] Bukur D B , Korranne M, Lang X, et al . Appl . Catal . A , 1995 ,126 : 85 —113
[68] Mansker L D , Jin Y, Bukur D B , et al . Appl . Catal . A , 1999 ,186 : 277 —296
[69] Bukur D B , Nowicki L , Manne R K, et al . J . Catal . , 1995 ,155 : 366 —375
[70] Bukur D B , Lang X, Ding Y. Appl . Catal . A , 1999 , 186 :255 —275
[71] Rao K R P M, Huggins F E , Mahajan V , et al . Hyperfine Interact . , 1994 , 93 : 1751 —1758
[72] Rao K R P M, Huggins F E , Mahajan V , et al . Hyperfine Interact . , 1994 , 93 : 1745 —1751
[73] Zimmerman W H , Bukur D B. Can. J . Chem. Eng. , 1990 , 68 :292 —300
[74] Donnelly T J , Satterfield C N. Appl . Catal . A , 1989 , 52 : 93 —99
[75] Dictor R A , Bell A T. J . Catal . , 1986 , 97 : 121 —133
[76] Donnelly R A , Yates I C , Satterfield C N. Energy Fuels , 1988 ,2 : 734 —739
[77] Lox E S , Froment GF. Ind. Eng. Chem. Sci . , 1993 , 32 : 61 —70
[78] Van Der Laan G P , Beenackers A C M. Catal . Rev. Sci . Eng. ,1999 , 41 (3/4) : 255 —318
[79] Donnelly T J , Satterfield C N. Appl . Catal . A , 1989 , 52 (1/2) :93 —114

[1] Hao Chen, Xu Xu, Chaonan Jiao, Hao Yang, Jing Wang, Yinxian Peng. Fabrication of Multifunctional Core-Shell Structured Nanoreactors and Their Catalytic Performances [J]. Progress in Chemistry, 2022, 34(9): 1911-1934.
[2] Xiaoguang Li, Xianglong Pang. Liquid Plasticines: Attributive Characters, Preparation Strategies and Application Explorations [J]. Progress in Chemistry, 2022, 34(8): 1760-1771.
[3] Peng Wang, Huan Liu, Da Yang. Recent Advances on Tandem Hydroformylation of Olefins [J]. Progress in Chemistry, 2022, 34(5): 1076-1087.
[4] Yang Linyan, Guo Yupeng, Li Zhengjia, Cen Jie, Yao Nan, Li Xiaonian. Modulation of Surface and Interface Properties of Cobalt-Based Fischer-Tropsch Synthesis Catalyst [J]. Progress in Chemistry, 2022, 34(10): 2254-2266.
[5] Di Pan, Peng Liu, Hongbin Zhang, Yi Tang. Continuous Flow Synthesis of Zeolites [J]. Progress in Chemistry, 2020, 32(7): 873-881.
[6] Hua Guo, Lei Zhang, Xu Dong, Gangyi Shen, Junfa Yin. Immobilized Multi-Enzyme Cascade Reactor [J]. Progress in Chemistry, 2020, 32(4): 392-405.
[7] Wanru Zhao, Xin Hu, Ning Zhu, Zheng Fang, Kai Guo. Ionic Polymerizations in Continuous Flow [J]. Progress in Chemistry, 2018, 30(9): 1330-1340.
[8] Hongtao Yu, Shuo Chen, Xie Quan*, Zhenhua Zhang. The Mechanism, Materials and Reactors of Photocatalytic Disinfection in Water and Wastewater Treatment [J]. Progress in Chemistry, 2017, 29(9): 1030-1041.
[9] Junying Lu, Yu Guo, Qirui Liu, Guangzhi Han, Zhou-jun Wang. Co-Based Catalysts for Carbon Dioxide Reforming of Methane to Synthesis Gas [J]. Progress in Chemistry, 2017, 29(12): 1471-1479.
[10] Jing Wang, Nan Yao*. Ni-Based Catalysts for Syngas Methanation Reaction [J]. Progress in Chemistry, 2017, 29(12): 1509-1517.
[11] Gong Wanjun, Zhao Zhiyong, Liu Simin*. Cucurbituril-Based Supramolecular Nanoreactors/Catalysts [J]. Progress in Chemistry, 2016, 28(12): 1732-1742.
[12] Guo Yan, Peng Bo, Zhang Chunyu, Zhang Xuequan. Morphology of Polypropylene in-Reactor Alloys [J]. Progress in Chemistry, 2015, 27(12): 1815-1821.
[13] Jia Sisi, Chao Jie, Fan Chunhai, Liu Huajie. DNA Origami Nanoreactors [J]. Progress in Chemistry, 2014, 26(05): 695-705.
[14] Shen Gangyi, Yu Wanting, Liu Meirong, Cui Xun. Preparation and Application of Immobilized Enzyme Micro-Reactor [J]. Progress in Chemistry, 2013, 25(07): 1198-1207.
[15] Huang Zhen, He Fang, Zhao Kun, Zheng Anqing, Li Haibin, Zhao Zengli. Synthesis Gas Production by Chemical-Looping Reforming of Methane Using Lattice Oxygen [J]. Progress in Chemistry, 2012, 24(08): 1599-1609.