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Progress in Chemistry 2003, Vol. 15 Issue (05): 420- Previous Articles   Next Articles

• Review •

Direct Hydroxylation of Benzene into Phenol

Ren Yongli;Wang Li**;Zhang Xiangwen   

  1. (School of Chemical Engineering, Tianjin University, Tianjin 300072, China)
  • Received: Revised: Online: Published:
  • Contact: Wang Li
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Recent progress of catalytic reactions for direct hydroxylation of benzene to phenol were reviewed, including anodic oxidation and catalytic oxidation with nitrous oxide, hydrogen peroxide or molecular oxygen. As oxidants all the reactions are environmentally friendly with high atomic economy. The relevant catalysts and active sites as well as the industrialization prospect of these reactions are also discussed.
Key words: benzene, hydroxylation, phenol, anode, nitrous oxide, hydrogen peroxide, molecular oxygen, catalyst

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