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Progress in Chemistry 2003, Vol. 15 Issue (02): 81-   Next Articles

• Review •

ploring New Route for Establishing the Theory of Catalysis on the Basis of Non-Equilibrium Thermodynamics

Wu Yue*;Yang Xiangguang   

  1. (Changchun Institute of Applied Chemistry,Chinese Academy of Sciences, Changchun 130022, China)
  • Received: Revised: Online: Published:
  • Contact: Wu Yue
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Conventional equilibrium thermodynamics has long been recognized as one of the most important cornerstone of the theory of heterogeneous catalysis, but it is not suited quite well to generalize the state and behavior of operating catalysts. It is principally to see that there are non-equilibrium processes involved. The catalytic system exits always in thermodynamically non-equilibrium state under which the state and behavior of the system depend upon both kinetics and thermodynamics. It is argued that the most general useful relation, relating kinetics and thermodynamics, is not the De Bonder inequality Ar≥,but the new equation of De Donde In r/r =A/R7\ What matter is not so much for theformal thermodynamic coupling between simultaneous overall reactions, but the kinetic coupling between the elementary processes of a catalytic sequence . By introducing the notion of chemical potential into the analysis of dynamic chemical phenomena, a joint kinetic-thermodynanmic approach allows one to analysis both catalytic reaction and non-equilibrium state of catalyst. Perspectively, the role of non-equilibrium thermodynamics in creating physic-chemical background for heterogeneous catalysis is in fact much more embracing and interesting than that given by conventional equilibrium thermodynamics.
Key words: catalysis, non-equilibrium thermodynamics, dissipative structure

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