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Progress in Chemistry 2002, Vol. 14 Issue (06): 433- Previous Articles   Next Articles

• Review •

Selective Redox Carbonylation to Ureas*

Mei Jianting1,2;Lu Shiwei1**   

  1. 1. National Engineering Research Center for Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian Chemphy Chemical Co. Ltd., Dalian 116011, China; 2.Department of the Three, Dalian Naval Institute, Dalian 116011, China
  • Received: Revised: Online: Published:
  • Contact: Lu Shiwei
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A new process for the synthesis of ureas based on the selective redox carbonylation of amine and nitro compounds was described. The mechanism of carbonylation, the catalyst systems, the reaction selectivity were comprehensively reviewed. The synthesis of symmetric ureas?unsymmetric ureas and cyclic ureas by palliadium-catalyzed or selenium-catalyzed were emphasized. The perspective in their applications was also discussed.
Key words: CO carbonylation, selective redox, amine, nitro compounds, ureas

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Abstract

Selective Redox Carbonylation to Ureas*