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Progress in Chemistry 2002, Vol. 14 Issue (03): 200- Previous Articles   Next Articles

• Review •

Clay-intercalated Metal Complex Catalysts and Their Molecular Recognition Catalysis

Tao Longxiang;Zou Duoxiu   

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  • Received: Revised: Online: Published:
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The expandable layers of clay provide useful two dimensional hosts which facilitate introduction of catalytical active metal complexes by cation exchange and ligand exchange methods. Intercalation of metal complexes into the interlamellar space of clay is an excellent method for homogeneous catalyst heterogenization. Clay-intercalated metal complex catalysts display molecular-recognizing catalysis, such as shape selectivity, steroselectivity, regioselectivity. The application of these heterogenized catalysts in the asymmetric hydrogenation, regioselective hydrogenation, regioselective carbonylation and steroselective arylation is described in this review. Clay-intercalated metal complex catalysts exhibit sufficiently high activity and selectivity to make them competitive to the homogeneous catalysts.
Key words: catalysts, clay, metal complexes, heterogenization, molecular recognition, regioselectivity

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