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Progress in Chemistry 2001, Vol. 13 Issue (05): 376- Previous Articles   Next Articles

• Review •

Review on Catalysis Mechanism of Methane Monooxygenase

Chen Jianbo;Xia Chungu;Xin Jiaying;Cui Junru;Li Shuben   

  1. State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences, Lanzhou 730000, China
  • Received: Revised: Online: Published:
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This paper presented the new results on catalysis reaction mechanism of methanemonooxy genase in recent years. Activation of the stable C—H bond of methane is thought to occur via either a radical rebound mechanism or a concerted in sertion of an oxygen atom. The studies using radical clock and quantum chemical calculations showed that there was not a consistent mechanism to clarify the reaction courses of methane monooxygenase. The type of mechanism may depend on source of methane monooxygenase or other factors. The spectro scopic analysis on the intermediates of methane monooxygenase accelerated the mechanism development of studies on methane monooxygenase.
Key words: methane monooxygenase, reaction mechanism, intermediates

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