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Progress in Chemistry 2001, Vol. 13 Issue (01): 33- Previous Articles   Next Articles

• Review •

The Application of Modified Heterogeneous Chiral Catalysts in Asymmetric Synthesis

Li Xiaodong;Lü Shijie;Chan Albert SC   

  1. State KeyLaboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China Department of Applied Biology and Chemical Technology,HongKong Polytechnic University, HongKong, China"
  • Received: Revised: Online: Published:
  • Contact: Lü Shijie
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The application of modified heterogeneous chiral catalysts in asymmetric synthesis is described in this review. Several types of heterogeneous catalytic systems, including immobilized transition metal complexes, chirally modified metal catalys s, chiral zeolite and clay2intercalated chiral catalysts, are summarized according to different preparative methods and catalytic reactions. The reaction mechanism intart rate modified catalysts and cinchona modified catalysts are also discussed.
Key words: asymmetric synthesis, heterogeneous catalysis, immobilization, chiral modification, chiral zeolite, clay2intercalated chiral catalysts

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