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Progress in Chemistry 2000, Vol. 12 Issue (03): 282- Previous Articles   Next Articles

• Review •

Review of Asymmetric Cyclopropanat ion of Olefins

Yao Xiaoquan;Chen Huilin;Zheng Zhuo*   

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
  • Received: Revised: Online: Published:
  • Contact: Zheng Zhuo
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In this article, the progress on asymmetric cyclopropanation of olefins during the last decade was reviewed. The application of chiral C2-symmetrical ligands in the reaction, such as bis2oxazoline and semicorrin, were discussed in detail. The new development of research on mechanism was in troduced. Some major difficulties in the industrial application of the reaction were summarized.
Key words: olefin, asymmetric cyclop ropanation, C2-symmetrical ligands

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