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Progress in Chemistry 2000, Vol. 12 Issue (03): 268- Previous Articles   Next Articles

• Review •

Recent Advances in the Synthesis of Liquid Hydrocarbon via Fischer-Tropsch Synthesis

Dai Xiaoping;Yu Changchun;Shen Shikong*   

  1. The Lab for Catalytic Conversion of Natural Gas, Petroleum University,Beijing 102200, China
  • Received: Revised: Online: Published:
  • Contact: Shen Shikong
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Conversion of natural gas to liquid hydrocarbon (GTL ) via Fischer Tropsch synthesis (FTS) is one of the main trends in the use of natural gas. Some corporations, such as Shell, Sasol, Exxon and Syntroleum , have developed their patent techniques of GTL , respectively. The products from GTL include fuel oil, base oil for lubricant, and other chemicals, which are environmentally friendly due to its lower S, N,metal content and aromatic hydrocarbon. With the developing in syngas manufactu re, catalyst preparation and process design of FTS, GTL compete with the product ion route from crude oil in economy in remote, small ormedium sized gas field. The recent advances in catalysts and processesare reviewed, and the trend of GTL in the future is discussed.It's of great importance to develop the technique in China.
Key words: natural gas, F-T synthesis, liquid hydrocarbon, catalysts, reactors

CLC Number: 

[1 ] 加藤顺, 小林博行, 村田义夫著, 金革等译, 碳一化学工业生产技术, 化学工业出版社, 北京, 1990,467—523.
[2 ] Badakhshan, 第十五届世界石油大会文集, 北京, 1997, 10, 665—678.
[3 ] Axelrod M G, Gaffney A M , Sofranko J et al. , Stud. Surf . Sci. Catal. , 1994, 81, 93—101.
[4 ] Jaguar B, 4th International Natural gas Conversion Symposium , FT 21, South Africa, 1995.
[5 ] Chem. Eng. , 1997, 104, 21.
[6 ] Van Wechem V M H, Senden M M G, Stud. Surf . Sci. Catal. , 1994, 81, 43—71.
[7 ] Chem. Eng. , 1997, 104, 39—40.
[8 ] Phodes A K Downstream , Oil & Gas Journal, 1996, 94, 85—86.
[9 ] Oil & Gas Journal, 1997, 95, 20.
[10 ] Ruchenstein E, J. Catal. , 1974, 35, 441—452.
[11 ] Dry M E, The Fischer-Tropsch Synthesis, in Catalysis: Sci. and Tech. , é , (eds J. R. Anderson,M. Boudart) , Springer-verlag, 1981, 160—251.
[12 ] Zhong B, Wang Q , Luo Q Y et al. , China-Jap an Bilateral Symp. on Effective Utilization of Carbon Resources, Guang Zhou, China, 1991, 69.
[13 ] 南照东(Nan Z D ) , 张志新(Zhang Z X) 等, 天然气化工(C1 化学与化工) (Natural Gas Chemical Industry , C1 Chemistry & Chemical Industry ) , 1992, 17 (3) , 24—28.
[14 ] Nosa O E, Charles W , Wojcichoski B W , Appl. Catal. , 1989, 55, 47—64.
[15 ] Hiroyuki I, Eiichi K, Appl. Catal. , 1990, 67, 1—9.
[16 ] Li X G, Zhong B, Peng S et al. , Catal. Lett. , 1994, 23, 245—250.
[17 ] O ’Brien R J , Xu L G, Spicer R Let al. , Catal. Today , 1994, 36, 325—334.
[18 ] Dragomir B B, Lech N , Lang X S, Catal. Today , 1995, 24, 111—119.
[19 ] Ajoy P R, Burtron H D, Catal. Today , 1997, 36, 335—345.
[20 ] Dragomir B B, Snehal A P,Lang X S, Appl. Catal. , 1994, 61, 329—349.
[21 ] Steininger M , Gryglewicz S, Science & Technology , 1994, 47 (3) , 115—116.
[22 ] 沈剑一( Shen J Y ) , 林励吾(Lin L W ) 等, 燃料化学学报(Journal of Fuel Chemistry and Technology ) , 1991, 19 (4) , 289—297.
[23 ] Wang D Z, Cheng X P, Huang Z E et al. , Appl. Catal. , 1991, 77, 109—122.
[24 ] Jager B, R Espinoza, Catal. Today , 1995, 23, 17—28.
[25 ] Inst. Francais DV Petrole. , E P 800 864, 1997.
[26 ] The British Petroleum Co. , CN 1 052 844, 1991.
[27 ] 斯塔特石油公司, CN 1 084 153, 1994.
[28 ] William C B, Kym B A , Charles H M et al. , US 5 545 674, 1996.
[29 ] Enrique I, Stuart L S et al. , J. Catal. , 1995, 153, 108—122.
[30 ] Tatsumi I, Nobuhiko H, Koichi E et al. , Appl. Catal. , 1990, 66, 267—282.
[31 ] Li F, Yoshii K, Yan S et al. , Catal. Today , 1997, 36, 295—304.
[32 ] Bessell S, Appl. Catal. A : General, 1993, 96, 253—268.
[33 ] Saul E C, Richard G C, Graham J H et al. , Appl. Catal. A : General, 1992, 84, 1—15.
[34 ] Enrique I, Stuart L S, Rocco A F et al. , J. Catal. , 1993, 143, 345—368.
[35 ] Bessell S, Stud. Sur. Sci. Catal. (Natural Gas Conversion ê ) , 1994 , 483—486.
[36 ] Rohr F, Holmen A , Barbo K et al. , Stud. Sur. Sci. Catal. (Natural Gas Conversion í , 1998,119, 107—112.
[37 ] Lapidus A , Krylova A , Ratbousky J et al. , Appl. Catal. A : General, 1992, 80, 1—11.
[38 ] Schluz H, Clawys M , Harms S, Stud. Sur. Sci. Catal. (Natural Gas Conversion ì ) , 1994, 107,193—200.
[39 ] Vada S, Kazi A M , Bedu-Addo F K et al. , Stud. Sur. Sci. Catal. (Natural Gas Conversion ê ) ,1994, 443—448.
[40 ] Van Berge P J , Stud. Sur. Sci. Catal. (Natural Gas Conversion ì ) , 1994, 107, 207—212.
[41 ] Klbel H, Ralek M , Catalyst Reviews-Science and Engineering , 1980, 21, 225—274.
[42 ] Yokota K, Hanataka Y, Fujimoto K, Fuel, 1991, 70, 989—994.
[43 ] Oil & Gas Journal, 1998, 96, 71—77.
[44 ] Oil & Gas Journal, 1994, 95, 16—21.
[45 ] Oil & Gas Journal, 1997, 95, 68—72.
[46 ] Hydrocarbon Processing , 1996, 75, 35.
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