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Progress in Chemistry 2000, Vol. 12 Issue (03): 255- Previous Articles   Next Articles

• Review •

Thermodynamics and Phase Equilibria of the Salt Lake Brine System at 25 ℃

Song Peng sheng;Yao Yan;Li Jun   

  1. Qinghai Institute of Salt Lakes, CAS, Xining 810008, China
  • Received: Revised: Online: Published:
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The salt lakes on the Qinghai-Xizang Plateau of China are famous for their high concentration of boron and lithium in brines. These brines mostly belong to the system Li+、Na+、K+、Mg2+(Ca2+)/Cl-，CO2-3(HCO-3)、SO2-4，borate-H2O (so called "Salt Lake Brine System") which is disserent from the classic sea water system and others. The phase diagram and solution properties of the salt lake brine system are obviously important for comprehensive utilization of brines and for investigation of the formation and evolution of Li, B-bearing salt lakes. Thermodynamics and phase equilibrium of the system are described with Pitzer ion interactio model of electrolyte solution. The prediction of phase equilibrium of the system Li+, K+, Mg2+/Cl-,SO2-4-H2O at 25。C is taken as an example to illustrate applicability and reliability of the model.

Key words: brine system, themodynamics, Pitzer ion interaction model

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