中文
Earlier issues
Announcement
More
Progress in Chemistry 1999, Vol. 11 Issue (04): 416- Previous Articles   Next Articles

• Review •

Chitin—a Novel Kind of Liquid Crystalline Polysaccharide

Dong Yanming;Wang Jianwei;Yuan Qing   

  1. Department of Materials Science, Xiamen University, Xiamen 361005, China
  • Received: Revised: Online: Published:
PDF ( 1547 ) Cited
Export

EndNote

Ris

BibTeX

The structures of two kinds of polysaccharide i. e. chitin and cellulose are compared, and the possibility for chitin to form liquid crystalline phase is discussed according to its structure and chain rigidity. Some chemical modification methods necessary for preparation of chit in derivatives with liquid crystalline behaviors are briefly summarized. The lyotropic liquid crystalline behaviors of fifteen chitin derivatives and then influence of structure factors are described. Liquid crystalline textures formed in solutions of chitin derivatives, for example fingerprint, alternative polarized field, banded and droplet textures, and thermotropic phase transition of chit in derivatives dichloroacetic acid solution are introduced. Fiber spinning from solutions of chitin and its derivatives including lyotropic liquid crystalline solutions are reviewed.

Key words: chitin, chitosan, derivatives, polysaccharides, liquid crystalline polymers, cholesteric phases, critical concentration, fiber spinning

CLC Number: 

[1 ] 严俊(Yan J ) , 化学通报(Chem. Bull. ) , 1984, (11) , 26—31.
[2 ] 周其凤(Zhou Q F) , 王新久(Wang X J ) , 液晶高分子(Liquid Crystal Polymers) , 科学出版社, 北京, 1994, 237.
[3 ] Werbowyj R S, Gray D G, Mol. Liq. Cryst. , 1976, 34 (Letters) , 97.
[4 ] Werbowyj R S, Gray D G, Macromolecules, 1980, 13, 69—73.
[5 ] Onogi Y, White J L , Fellers J F, J. Polym. Sci. Polym. Phys. , 1980, 18, 663—682.
[6 ] Aharoni S, Mol. Liq. Cryst. , 1980, 36 (Letters) , 237.
[7 ] 黄勇(Huang Y) , 李泮通(Li P T ) , 化学通报(Chem. Bull. ) , 1985, (2) , 19—24.
[8 ] Ogura K, Kanamoto T , Sannan T et al. , Chitin Chitosan Proceeding Int. Conf . 2nd , Tottori, Japan,1982, 39—44.
[9 ] Sakurai K, Takahashi T , 纤维学会志(Sen2i Gakkaishi) , 1988, 93 (3) , 147—151.
[10 ] Sakurai K, Miyata M , Takahashi T , 纤维学会志(Sen2i Gakkaishi) , 1990, 46 (2) , 79—81.
[11 ] Rout D K, Pulapura S K, Gross R A , Macromolecules, 1993, 26 (22) , 5999—6006.
[12 ] Rout D K, Pulapura S K, Gross R A , Macromolecules, 1993, 26 (22) , 6007—6010.
[13 ] Rout D K, Barman S P, Pulapura S K et al. , Macromolecules, 1994, 27 (11) , 2945—2950.
[14 ] 董炎明(Dong Y M ) , 张景(Zhang J ) , 高等学校化学学报(Chem. J. Chin. Univ. ) , 1996, 17(6) , 973—977.
[15 ] Bianchi E, Ciferri A , Conio G et al. , Macromolecules, 1985, 18, 646—650.
[16 ] Bianchi E, Ciferri A , Conio G et al. , Macromolecules, 1986, 19, 630—636.
[17 ] Noel C, Navard P, Prog. Polym. Sci. , 1991, 16, 55—110.
[18 ] Terbojevich M , Carraro C, Cosani A et al. , Carbohydr. Res. , 1988, 180, 73—86.
[19 ] Terbojevich M , CosaniA , Conio G et al. , Carbohydr. Res. , 1991, 209, 251—260.
[20 ] Cavlstom D, J. Bioch. Cytol. , 1957, 3, 669.
[21 ] Blackwell J , Parker K D, Rusall K M , J. Mol. Biol. , 1967, 28, 383.
[22 ] 高洁(Gao J ) , 汤烈贵(Tang L G) , 纤维素科学(Cellulose Science) , 科学出版社, 北京, 1996, 41.
[23 ] Kaifu K, Nishi N , Komai T et al. , Polym. J. , 1981, 13 (3) , 241—245.
[24 ] Nishi N , Noguchi J , Tokura S et al. , Polym. J. , 1979, 11 (1) , 27—32.
[25 ] Somorin O , Nishi N , Tokura S et al. , Polym. J. , 1979, 11 (5) , 391—396.
[26 ] Nishi N , Ohnuma H, Nishimura S et al. , Polym J. , 1982, 14 (11) , 919—923.
[27 ] Grant S, Blair H S, Mckay G, Makromol. Chem. , 1989, 190, 2279.
[28 ] Grant S, Blair H S, Mckay G, Polymer Communications, 1988, 29, 342—344.
[29 ] Nishimura S, Kohgo O , Kurita K, Chem. Lett. , 1990, 243—246.
[30 ] 平野茂博, 化学(Chemistry ) , 1988, (3) , 155—160.
[31 ] 蒋挺大(Jiang T D) , 甲壳素(Chitin) , 中国环境科学出版社, 北京, 1994, 117—215.
[32 ] Tokura S, Yoshida J , NishiN et al. , Polym. J. , 1982, 14 (7) , 527—536.
[33 ] 王爱勤(Wang A Q ) , 俞贤达(Yu X D) , 功能高分子学报(J. Functional Polym. ) , 1998, 11 (1) ,81.
[34 ] 包光迪(Bao G D) , 甲壳质的利用(Applications of Chitin) , 科技卫生出版社, 北京, 1958, 36.
[35 ] Kim S S, Kim S J , Moon Y D, Polymer, 1994, 35 (15) , 3212—3216.
[36 ] Tokura S, Nishi N , TsutsumiA et al. , Polym. J. , 1983, 15, 485—552.
[37 ] Shigemasa Y, Ishida A , Sashiwa H et al. , Chemistry Letters, 1995, 623—624.
[38 ] Miyata S, Tasaka S, Masuda Y et al. , Polym. J. , 1983, 15 (7) , 553—556.
[39 ] Kim J H, Lee Y M , Polymer, 1993, 34 (9) , 1952—1957.
[40 ] Muzzarelli R A A , Tanfani F, Carbohydr. Polym. , 1985, 5, 297.
[41 ] Hermans J , J. Colloid Sci. , 1962, 17, 638.
[42 ] Dong Y M , Li Z Q , Chin. J. Polym. Sci. , 1999, 17 (1) : 65—70.
[43 ] 董炎明(Dong Y M ) , 李志强(Li Z Q ) , 化学通报(Chem. Bull. ) , 1998, (6) , 39—42.
[44 ] 董炎明(Dong Y M ) , 李志强(Li Z Q ) , 天然产物研究与开发(Natural Product Researchand Development) , 1998, 10 (2) , 41—45.
[45 ] 董炎明(Dong Y M ) , 袁清(Yuan Q ) , 肖滋兰(Xiao Z L ) 等, 高等学校化学学报(Chem. J. Chin.Univ. ) , 1999, 20 (1) , 140—145.
[46 ] Conio G, Bianchi E, Ciferri A et al. , Macromolecules, 1983, 16, 1264—1269.
[47 ] Flory P J , Proc. Royal. Soc. Lond. Ser A , 1956, 234, 60—72.
[48 ] 董炎明(Dong Y M ) , 李志强(Li Z Q ) , 郭榕(Guo R) , 高等学校化学学报(Chem. J. Chin. Univ. ) ,1998, 19 (1) , 161—163.
[49 ] 董炎明(Dong Y M ) , 李志强(Li Z Q ) , 功能高分子学报(J. Functional Polym. ) , 1998, 11 (1) ,87—90.
[50 ] 董炎明(Dong Y M ) , 李志强(Li Z Q ) , 广州化学(Guangzhou Chem. ) , 1997, (4) , 24—29.
[51 ] Dong Y, Li Z, Polym. J. , 1998, 30 (3) , 272—273.
[52 ] 董炎明(Dong Y M ) , 李志强(Li Z Q ) , 高分子学报(Acta Polymerica Sinica) , 1998, (3) , 282—286.
[53 ] Navard P, Haudin J M , Dayan S et al. , J. Polym. Sci. Polym. Lett. E d. , 1981, 19, 379—385.
[54 ] 胡钟鸣(Hu Z M ) , 吴大诚(Wu D C) , 孙玉山(Sun Y S) 等, 第六届全国高分子液晶态学术会议论文集, 湘潭, 1998, 46—47.
[55 ] Laivins G V , Gray D G, Polymer, 1985, 26, 1435—1442.
[56 ] Dayan S, Maissa P, Vellutini M J et al. , J. Polym. Sci. Lett. E d. , 1982, 20, 33—43.
[57 ] 野口顺藏, 和田理, 濑尾宽等, 高分子化学(Chem. Polym. ) , 1973, 30 (338) , 320—325.
[58 ] Tokura S, Nishi N , Noguchi J , Polym. J. , 1979, 11 (10) , 781—786.
[59 ] Rathke T D, Hudson S M , J. Macromol. Sci. 2 Reviewsin Macromol. Chem. Phys. , 1994, 34(3) , 375—437.
[60 ] 莫秀梅(Mo X M ) , 周涵新(Zhou H X) , 孙桐(Sun T ) , 中国纺织大学学报(J. China Textile Univ. ) ,1993, 19 (6) , 90—94.
[61 ] Tokura S, Nishi N , Somorin O et al. , Polym. J. , 1980, 12 (10) , 695—700.
[62 ] Tokura S, Yoshida J , Nishi N et al. , Polym. J. , 1982, 14 (7) , 527—536.
[63 ] Szosland L , East G C, J. Appl. Polym. Sci. , 1995, 58, 2459—2466.
[64 ] East G C, Qin Y, J. Appl. Polym. Sci. , 1993, 50, 1773—1779.
[65 ] 白井汪芳, 小山俊树, 户仓清一, 高分子加工, 1994, 43 (12) , 2—5.
[66 ] Wei Y C, Hudson S M , Mayer J M et al. , J. Polym. Sci. , Polym. Chem. , 1992, 30, 2187—2193.
[67 ] 中国化纤总公司, 化学纤维及原料实用手册, 中国纺织出版社, 北京, 1996, 404.
[68 ] 细川纯(Hosokawa J ) , 西山昌史(Nishiyama M ) , 高分子(Kobunshi) , 1990, 39 (4) , 276—279.
[69 ] 筏羲人( Ikada Y) , 高分子(Kobunshi) , 1987, 36 (6) , 422—425.
[1] Yumeng Wang, Rong Yang, Qijiu Deng, Chaojiang Fan, Suzhen Zhang, Yinglin Yan. Application of Bimetallic MOFs and Their Derivatives in Electrochemical Energy Storage [J]. Progress in Chemistry, 2022, 34(2): 460-473.
[2] Xiaohan Hou, Shengnan Liu, Qingzhi Gao. Application of Small-Molecule Fluorescent Probes in the Development of Green Pesticides [J]. Progress in Chemistry, 2021, 33(6): 1035-1043.
[3] Jianyun Lin, Shihe Luo, Chongling Yang, Ying Xiao, Liting Yang, Zhaoyang Wang. Bio-Based Polymeric Hemostatic Material and Wound Dressing [J]. Progress in Chemistry, 2021, 33(4): 581-595.
[4] Zhichao Liu, Hongliang Mu, Yan Li, Liu Feng, Dong Wang, Guangwu Wen. Application of Metal-Organic Frameworks-Derived Conversion-Type Anodes in Alkali Metal-Ion Batteries [J]. Progress in Chemistry, 2021, 33(11): 2002-2023.
[5] Jing Wen, Yuhong Li, Li Wang, Xiunan Chen, Qi Cao, Naipu He. Carbon Dioxide Smart Materials Based on Chitosan [J]. Progress in Chemistry, 2020, 32(4): 417-422.
[6] Ni Huang, Feng Xu, Jiangbin Xia. Solid State Polymerization of Polythiophene and Its Applications [J]. Progress in Chemistry, 2019, 31(8): 1103-1115.
[7] Kun Cao, Bei Yuan, Xue Liu, Minfang Wu, Zhen Yao*. Preparation and Applications of the Chiral Norbornene Derivatives [J]. Progress in Chemistry, 2017, 29(6): 605-616.
[8] Fu Kaiqiao, Zhang Guangyan, Jiang Xulin. Synthesis and Application of Polyaspartamide Derivatives for Drug/Gene Delivery [J]. Progress in Chemistry, 2016, 28(8): 1196-1206.
[9] Hu Xiangzheng, Wang Jianmin. Preparation and Application of Chenodeoxycholic Acid and Its Derivatives [J]. Progress in Chemistry, 2016, 28(6): 814-828.
[10] Gao Peng, Gao Binbin, Gao Jianqiang, Zhang Kai, Yang Yongping, Chen Hongwei. Chitosan and Its Composites for Removal of Mercury Ion from Aqueous Solution [J]. Progress in Chemistry, 2016, 28(12): 1834-1846.
[11] Guan Li, Zhang Xiaoyuan, Sun Fuqiang, Jiang Yue, Zhong Yiping, Liu Ping. Oligothiophene Derivatives in Organic Photovoltaic Devices [J]. Progress in Chemistry, 2015, 27(10): 1435-1447.
[12] Wang Yihan, Wakisaka Minato. Nanofiber Fabrication Techniques and Its Applicability to Chitosan [J]. Progress in Chemistry, 2014, 26(11): 1821-1831.
[13] Weng Xilun, Bao Zongbi, Luo Fei, Su Baogen, Yang Yiwen, Ren Qilong. Progress in Preparation and Applications of Cellulose Derivatives-Based Chiral Stationary Phase [J]. Progress in Chemistry, 2014, 26(0203): 415-423.
[14] Zhou Guifeng, Wang Qin, Zeng Renquan, Fu Xiangkai, Yang Xinbin. Preparation and Application of Zirconium Phosphate and Its Derivatives [J]. Progress in Chemistry, 2014, 26(01): 87-99.
[15] Su Bin, Zhao Jing, Liu Chunbo, Che Guangbo, Wang Qingwei, Xu Zhanlin. Small Molecular Organic Electroluminescent Materials Based on 8-Hydroxyquinoline and Its Derivatives [J]. Progress in Chemistry, 2013, 25(07): 1090-1101.