中文
Announcement
More
Progress in Chemistry 1999, Vol. 11 Issue (01): 49- Previous Articles   Next Articles

• Review •

Steady State Isotopic Transient Kinetic Analysis

Li Chunyi;Shen Shikong**   

  1. The Laboratory for Catalytic Conversion of Natural Gas,University of Petroleum, Beijing 102200, China
  • Received: Revised: Online: Published:
  • Contact: Shen Shikong
PDF ( 2171 ) Cited
Export

EndNote

Ris

BibTeX

Steady state iso topic transient kinetic analysis (SSITKA ) is a powerful technology to study heterogeneous catalytic reactions, by which the reaction mechanisms and other in situkinetic information, such as quantity, life, coverages of in term ediates,rate constant of elementary reaction, quantity and distribution of reactive sites can be obtained. In the present paper, the apparatus of SS ITKA , reactors, acquirement of kinetic parameters, inference of reaction mechanisms, and the combination of SS ITKA with insitu FTIR were summarized.

CLC Number: 

[1 ] Happel J , J. Chem. Eng. Sci. , 1978, 33, 1567.
[2 ] Happel J , Suzuki I, Kokayeff P, Fthenakis V , J. Catal. , 1980, 65, 59—77.
[3 ] Shannon S L , Goodwin J G Jr, Chem. R ev. , 1995, 95, 677—695.
[4 ] Efstathiou A M , KladiA , TsipouriariV A , V erykios X E, J. Catal. , 1996, 158, 64—75.
[5 ] KrollV C H, Sw aan H M , L acombe S, Mirodatos C, J. Catal. , 1997, 164, 387—398.
[6 ] Tsipouriari V A , Efstathiou A M , V erykios X E, J. Catal. , 1996, 161, 31—42.
[7 ] Schuurman Y, Mirodatos C, Applied Catalysis A : General, 1997, 151, 305—331.
[8 ] Shannon S L , Goodwin J G Jr, Applied Catalysis A : General, 1997, 151, 3—26.
[9 ] Nwalor J U , Goodwin J G Jr, Biloen P, J. Catal. , 1989, 117, 121—134.
[10 ] Van Der Linde S C, Nijhuis T A et al. , Applied Catalysis A : General, 1997, 151, 27—57.
[11 ] Nibbelke R H, Scheerova J , De Croon M H J M , Marin G B, J. Catal. , 1995, 156, 106—119.
[12 ] Stockwell D M , Bennett C O , J. Catal. , 1988, 110, 354—363.
[13 ] Chen B, Goodwin J G Jr, J. Catal. , 1995, 154 , 1—10.
[14 ] Zielinski J , React. Kinet. Catal. Lett. , 1981, 17, 69—75.
[15 ] Stockwell D M , Chung J S, Bennett C O , J. Catal. , 1988, 112, 135—144.
[16 ] Efstathiou A M , Bennett C O , J. Catal. , 1989, 120, 137—156.
[17 ] Happel J , Walter E, Lecourtier Y, J. Catal. , 1990, 123, 12—20.
[18 ] Biloen P, J. Mol. Catal. , 1983, 21, 17—24.
[19 ] De Pontes M , Yokomizo G H, Bell A T , J. Catal. , 1987, 104, 147—155.
[20 ] Biloen P, Helle J N , van Den Berg F G A , Sachtler W M H, J. Catal. , 1980, 81, 450—463.
[21 ] Hoost T E, Goodwin J G Jr, J. Catal. , 1992, 134, 678—690.
[22 ] Scott K F, Phillips C S G, J. Chromatogr. Sci. , 1983, 21, 125.
[23 ] Scott K F, J. Chem. Soc. , Faraday Trans. , 1980, 76, 2065.
[24 ] Soong Y, Krishna K, Biloen P, J. Catal. , 1986, 97, 330—343.
[25 ] Winslow P, BellA T , J. Catal. , 1984, 86, 158—172.
[26 ] Cant N W , BellA T , J. Catal. , 1982, 73, 257—271.
[27 ] McWhirter J G, Pike E R, J. Phys. A , 1978, 11, 1729.
[28 ] McWhirter J G, Opt. Acta, 1980, 27, 83.
[29 ] Ostrowsky N , Sornette D, Parker P, Pike E R, Opt. Acta, 1981, 28, 1059.
[30 ] Biloen P, Helle J N , van Den Berg F G A , Sachtler W M H, J. Catal. , 1983, 80, 450.
[31 ] Kobayashi H, Kobayashi M , Catal. R ev. -Sci. Eng. , 1974, 10, 139.
[32 ] Balakos M W , Chuang S S C, Srinivas G, J. Catal. , 1993, 140, 281—285.
[33 ] Yokomizo G H, Bell A T , J. Catal. , 1989, 119, 467—482.
[34 ] Efstathiou A M , Chafik T , Bianchi D et al. , J. Catal. , 1994, 148, 224—239.
[35 ] Li Y E, Boecker D, Gonzalez R D, J. Catal. , 1988, 110, 319—329.
[36 ] Chuang S S C, Pien S I, J. Catal. , 1992, 135, 618—634.

[1] Xun Wang, Wei Yuan, Xinbin Feng. Global Review of Mercury Biogeochemical Processes in Forest Ecosystems [J]. Progress in Chemistry, 2017, 29(9): 970-980.
[2] Zhang Yuan, Qi Shihua* . Techniques of Stable Chlorine Isotope Analysis and Relevant Applications in Research of Organochlorine Pollutants [J]. Progress in Chemistry, 2012, 24(12): 2384-2390.
[3] Fang Qile, Chen Baoliang*. Natural Origins, Formation Mechanisms, and Fate of Environmental Perchlorate [J]. Progress in Chemistry, 2012, (10): 2040-2053.
[4] Gu Zhi-Guo, Li Zaijun, Yang Jie. Advance in Lithium Isotope Separation [J]. Progress in Chemistry, 2011, 23(9): 1892-1905.
[5] . Characterization of Methanogenesis Using Stable Isotopic Probing [J]. Progress in Chemistry, 2009, 21(0203): 540-549.
[6] Qiu Xiaoyan1,2  Cui Meng1 Liu Zhiqiang1 Liu Shuying1**. Protein Disulfide Bond Determination and Its Analysis by Mass Spectrometry [J]. Progress in Chemistry, 2008, 20(06): 975-983.
[7] Xiaohui Long1,Zhihong Mo2,Yaozhou Zhang3**. Quantitative Analytical Techniques of Proteins Based on Two-Dimensional Gel Electrophoresis [J]. Progress in Chemistry, 2006, 18(04): 474-481.