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Progress in Chemistry 1998, Vol. 10 Issue (02): 158- Previous Articles   Next Articles

• Review •

Routes of Substitution for Liquid Acid Catalysts

Wu Yue   

  1. Changchun Institute of Applied Chemistry,Chinese Academy of Sciences, Changchun 130022, China
  • Received: Revised: Online: Published:
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Superior solid acid catalysts are needed for existing industrial processes and for environmental considerations, especially for those using conventional liquid acids, i. e.H2SO4, HF,AlCl3 etc. as catalyst s in homogeneou s system s. Recen t ly, by con sidering the similarities between acid sites (cen ters) playing decisive role in both homogeneous and heterogeneous acid catalytic processes, based on the refined theory of homogeneous acid catalysis in liquid phase, and through the analysis of the nature of different kinds of acid sites(Lewis,Bronsted and super acids) , an unique model of acid structure for superior solid acid has been proposed, and thus the tailoring of several different forms of solid acid catalysts might be allowed.

Key words: acid catalysis, liquid acids, solid acids, superacids, substitution

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[1 ] 吴越, 催化化学(上, 下册) , 科学出版社, 北京, 1990, 第三章; 1995, 第九章.
[2 ] 吴越, 工业催化, 1994, 2 (4) , 3- 15.
[3 ] Malinowiki S, Marccczewski M ,in Catalysis, Vol. 8, Chapter 4.
[4 ] Knozinger H, Ratnassamy P, Catal. Rev-Sci. Eng. , 1978, 17, 31.
[5 ] Ghorbel A , Hoang-Van C, Teichner S J , J. Catal. , 1973, 10, 298.
[6 ] Bratsch S G, J. Chem. Edu. , 1988, 68 (10) , 877- 878.
[7 ] Thomas C L , Ind. Eng. Chem. , 1949, 41, 2654.
[8 ] Tanabe K, Sumiyoshi T , Kitagava J et al. , Bull. Chem. Soc. Jan. , 1974, 47, 1064.
[9 ] Shibata K, Kiyonra T , Kitagava J et al. , Bull. Chem. Soc. Jan. , 1973, 46, 2985.
[10 ] HallN F, Conant J B, J. Am. Chem. Soc. , 1927, 49, 3047, 3062.
[11 ] Meerwein H, Ann. Chem. Leipzig , 1927, 455, 227; 1931, 484, 1.
[12 ] Gillespie R, J. Can. Chem. Edu. , 1969, 4, 9.
[13 ] Hammett L P, Deyrup A J , J. Am. Chem. Soc. , 1932, 54, 1271.
[14 ] Gillespie R J , Moss K C, J. Chem. Soc. , 1966, 1170.
[15 ] Siskin M , Schlosberg R H, Kocsi W P, Industrialand Laboratory Alkylations, ASC Symp. Ser. ,No 55, 1977, 186.
[16 ] Olah G M , Commeyras A , J. Am. Chem. Soc. , 1969, 91, 2929.
[17 ] Magnotta V L , Gates B C, J. Catal. , 1977, 46, 266.
[18 ] Olah G A , Meidar D, Nou V , J. Chim. , 1979, 3, 269.
[19 ] Tanabe K, Hatton H, Chem. Lett. , 1976, 625.
[20 ] Chenley H A , Raymond C L , Trans. Am. Inst. Chem. Eng. , 1946, 42, 595.
[21 ] Krzywiski A , Marczewski M , J. Chem. Soc. , Faraday I , 1980, 76, 1311.
[22 ] Goble A G, Lawrance P A , Proc. 3rd Int. Congr. Catal. Amsterdam , Vol. 1, 1964, Wiley, New York, 1965, 320.
[23 ] Ronmeyons A , Franck J P, Montwnal C R, Acad Sc Paris Serc, 1977, 284, 593.
[24 ] Ono Y, Tanake T , Kitajima N , Chem. Lett. , 1979, 56, 47.
[25 ] Lalancette J M , Lafontaine J , J. Chem. Soc. , Chem. Commun. , 1973, 815.
[26 ] Arata K, Appl. Catal. A , 1996, 146, 3- 32.
[27 ] КазанскийВБ, Усп. Хим. , 1988, 57 (12) , 1937- 1962.
[28 ] Sanderson R T , Chemical Bondsand Bond Energy , 2nd. , Acad. Press, New York, 1976.
[29 ] Carniti P, Gervasini A , Auroux A , J. Catal. , 1994, 150, 274- 283.
[30 ] 催化剂手册(按元素分类) , 化学工业出版社, 北京, 1982.
[31 ] ЗамараевКИ, ЖибомировГМ, Изв. Сиб. Отб. Ан. СССР. Сер. Хим. Наук, 1987, 12 (4) , 3- 7.
[32 ] Olah G A ,in Friedel Craftsand Related Reactions (ed. Olah G A ) , Vol. 1, Intersciences, New York, 1964.
[33 ] Benegi H A , Winquist B H, Adv. Catal. , 1978, 27, 97.
[34 ] Marcgewski M , Derewinski M , Malinowski S, Can. J. Chem-Eng. , 1983, 61, 93.
[35 ] Yoshida S, Kawakami H,in Acid -Base Catalysis (eds. Tanake K, Hattori H, Yamaguchi T et al. ) ,Kodawsha VCH, 1988, 123- 138.
[36 ] Menaudeau P, Nacucku C, Catalysis Today , 1996, 31 (3- 4) , 265- 273.
[37 ] Gutierrey E, Aznar A J , Ruiz-Hitzky E,in Heterogeneous Catalysisand Fine Chemicals I I (eds.Guisnet M , Barrauet J , Bouchoule C et al. ) , Elesevier, 1991, 539- 547.
[38 ] Tada A ,in Acid-Base Catalysis (eds. Tanake K, HattoriH, Yamaguchi T et al. ) , Kodawsha VCH,1988, 439- 452.
[39 ] Matsuhashi H, Hino M , Arata K,ibid. , 357- 362.
[40 ] Mikaida K, Miyashi T , Saton T ,ibid. , 363- 369.
[41 ] КажевниковИВ, МатвеевКИ, Усп. Хим. , 1982, 51 (11) , 1875- 1896.
[ 42 ] Okamoto T , Imanaka T ,in Acid-Base Catalysis (eds. Tanake K, Hattori H, Yamaguchi T et al. ) ,Kodawsha VCH, 1988, 224- 229.
[ 43 ] Bernholc J , Horsley J A , MurrellL L , Sherman L G, Soled S, J. Phys. Chem. , 1987, 91, 1526-1530.
[ 44 ] Iwasawa Y,in Acid-Base Catalysis (eds. Tanake K, Hattori H, Yamaguchi T et al. ) , Kodawsha VCH, 1988, 267- 280.
[45 ] Knozuiger H,ibid. , Kodawsha VCH, 1988, 147- 167.
[46 ] ПаукштисЕА, ЮрченкоЭН, Усп. Хим. , 1983, 52 (3) , 426- 454.
[47 ] Hasegawa S, Kudo M , Tanaka T ,in Acid -Base Catalysis (eds. Tanake K, Hattori H, Yamaguchi T et al. ) , Kodawsha VCH, 1988, 2- 6, 183- 190.
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