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Progress in Chemistry 1998, Vol. 10 Issue (02): 137- Previous Articles   Next Articles

• Review •

Selective Oxidation of Hydrocarbons Using Lattice Oxygen of Catalyst as Oxidant

Shen Shikong;Min Enze   

  1. The Laboratory for Catalytic Conversion of Natural Gas,University of Petroleum , Beijing 102200, China; SINOPEC Research Institute of Petroleum Processing, Beijing 100083, China
  • Received: Revised: Online: Published:
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A ccording to the redox mode, the selective oxidation of hydrocarbons using lattice oxygen as oxidant could be implemented in the following manner: a riser reactor for oxidation of hydrocarbon with lattice oxygen to form product, a regenerator for reoxidation of catalyst by air to restore its initial state. There are several advan tages in the separation of redox process comparing with cofeed mode: (1) A high selectivity of product could be obtained, because nonselective oxidation could be inhibited in the absence of gas phase oxygen; (2) A highly concentrated hydrocarbon feed stream could be used due to no trouble with explosion limit, that results in a simpler separation of the products and the recovery of unconverted hydrocarbon feed for recycle. This new technology is very useful for selective oxidation of hydrocarbons to save raw materials, improve environment and enhance economic benefit. In this paper, the current research and advances, the facing challenges, and the potential applications of the selective oxidation of hydrocarbons with lattice oxygen are briefly reviewed.

Key words: hydrocarbons, lattice oxygen, selective oxidation, redox mechanism, circulating fluidized bed (CFB)

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[1 ] Lewis W K, Gilliland E R, Reed W A , Ind. Eng. Chem. , 1949, 41, 1227.
[2 ] Haggin J , C&EN , 1995, 73 (Apr. 3) , 21.
[3 ] Grasselli R K, Burrington J D, Adv. Catal. , 1981, 30, 133.
[4 ] Moro-Oka Y, Ueda W , Adv. Catal. , 1994, 40, 233.
[5 ] Mars P, Van Krevenlen D W , Chem. Eng. Sci. , 1954, 3 (Suppl. ) , 341.
[6 ] Haber J , Stud. Surf . Sci. Catal. , 1992, 72, 279.
[7 ] Fujimoto K, Stud. Surf . Sci. Catal. , 1994, 81, 73.
[8 ] Callahan J L , Grasselli R K, Miberger E C, Strecker H A , Ind. Eng. Chem. Prod. Res. Develop. ,1970, 9 (2) , 134.
[9 ] Schwendeman M N , McBrige R, Reuter D, Isaacs M , Chem. Process. , 1983, (Jul. ) , 100.
[10 ] Emig G, Martin F, Catal. Today , 1987, 1, 477.
[11 ] Contractor R M , Bergna H E, Horowitz H S et al. , Catal. Today , 1987, 1, 49.
[12 ] Contractor R M , Sleight A W , Catal. Today , 1988, 3, 175.
[13 ] Contractor R M , Garnett B I, Horowitz H S et al. , Stud. Surf . Sci. Catal. , 1994, 82, 233.
[14 ] Centi G, Catal. Today , 1993, 16 (1) , 5.
[15 ] Abon M , Bere K E, Delichere P, Catal. Today , 1997, 33, 15.
[16 ] Emig G, Uihlein K, Hacker C J , Stud. Surf . Sci. Catal. , 1994, 82, 243.
[17 ] Keller G E, Bhasin M M , J. Catal. , 1982, 7, 39.
[18 ] Lunsford J H, Catal. Today , 1990, 4, 235.
[19 ] Fox III J M , Catal. Rev.-Sci. Eng. , 1993, 35 (2) , 169.
[20 ] Sofranko J A , L eonard J J , Jones C A , J. Catal. , 1987, 103, 302.
[21 ] Jones C A , L eonard J J , Sofranko J A , J. Catal. , 1987, 103, 331.
[22 ] ARCO , US 4 777 313, 1985.
[23 ] Patience G S, Mills P L , Stud. Surf . Sci. Catal. , 1994, 82, 1- 18.
[24 ] Pugsley T S, Patience G S, Berruti F, Chaouki J , Ind. Eng. Chem. Res. , 1992, 31, 2652- 2660
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