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Progress in Chemistry 1996, Vol. 8 Issue (02): 155- Previous Articles   Next Articles

• Review •

Progress in Study on Molecular Thermodynamic Model for Electrolyte Solution

Li Yigui;Li Chunxi   

  1. (Department of Chemical Engineering, Tsinghua University, Beijing 100084, China)
  • Received: Revised: Online: Published:
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A review of thermodynamic study for electrolyte solution in recent years is presented from three aspects,i.e., traditional solution theory or semiempirical model, advanced statistical mechanics theory and molecular simulation. It is pointed out that the main tendency of this study is gradually turned from the traditional solution theory or semiempirical model to statistical mechanics theory , from primitive to nonprimitive electrolyte model, in o rder to estab lish the mo lecu lar thermodynam ic model at h igh level,which can predict them acroscopic thermodynamic properties of electrolyte solution system from the microscopic molecular and ionic parameters.

Key words: electrolyte solution, molecular thermodynamic model, traditional solution theory, statistical mechanics theory, molecular simulation

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