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Progress in Chemistry 1996, Vol. 8 Issue (01): 57- Previous Articles   Next Articles

• Review •

Asymmetric Catalytic Epoxidation Reactions

Zhang Yiliang;Yang Zhenyun   

  1. (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012)
  • Received: Revised: Online: Published:
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The developments of asymmetric catalytic epoxidation systems were reviewed,with emphasis on the inspiring results and promising application of asymmetric epoxidation of unfunctionalized cis-olefins catalyzed by optical active(salen) Mn()complexes [salen=N'-ethylenebis( salicylideneaminato)],as well as the merits, mechanism, new developments and applications of Sharpless-Katsuki asymmetric epoxidation.

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Abstract

Asymmetric Catalytic Epoxidation Reactions