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Progress in Chemistry 2024, Vol. 36 Issue (3): 367-375 DOI: 10.7536/PC230718 Previous Articles   Next Articles

• Review •

Application of MOFs in Catalytic Conversion of Organic Molecules

Xichen Li1,2, Zheng Li1,2, Can Peng1,2, Chen Qian1,2, Yufei Han1,2, Tao Zhang1,2()   

  1. 1 Department of Radiopharmaceuticals, School of Pharmacy, Nanjing Medical University, Nanjing 211166, China
    2 Nuclear Medicine Clinical Transformation Center, Nanjing Medical University, Nanjing 210029, China
  • Received: Revised: Online: Published:
  • Contact: * e-mail: zhangtaocjh@njmu.edu.cn
  • Supported by:
    National Natural Science Foundation of China(12275135); Jiangsu Province University Natural Science Research Project(21KJB350015); Nanjing Medical University Talent Introduction Research Start-up Fund(NMUR20210003); Key Project of Connotation Construction of Nanjing Medical University and Science and Technology Development Fund of Nanjing Medical University(NMUB20210014); Jiangsu Province University Natural Science Research Project(22KJB350008)
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Metal-organic framework compounds (MOF), also known as porous coordination polymers, are a new type of organic-inorganic hybrid porous materials which are self-assembled from organic ligands and metal ions, and are an important part of nanomaterials. Compared to other porous materials, MOFs have a large surface area, high porosity and adjustable structure and properties, making them have a good application prospect in heterogeneous catalysis. In this paper, the background of MOFs catalysis is briefly reviewed, followed by a review and prospect of the recent progress of MOFs in catalytic conversion reactions of organic molecules, in order to provide a reference for the design and development of organic reactions catalyzed by MOFs.

Contents

1 Introduction

2 Knoevenagel Condensation catalyzed by MOFs

3 Suzuki-Miyaura Reaction catalyzed by MOFs

4 Mizoroki-Heck Reaction catalyzed by MOFs

5 Aldol Condensation catalyzed by MOFs

6 A3-Coupling Reaction catalyzed by MOFs

7 Cycloaddition of CO2 catalyzed by MOFs

8 Oxidation and reduction of unsaturated hydrocarbons catalyzed by MOFs

9 Conclusion and outlook

Key words: metal-organic framework, heterogeneous catalysis, interfacial organometallic chemistry, organic molecules, high value-added chemicals
Fig. 1 Diagram of Knoevenagel condensation reaction
Fig. 2 Diagram of UiO-66 and its modifications[13]
Fig. 3 Diagram of Suzuki-Miyaura reaction
Fig. 4 Diagram of UiO-66 (L3) [21]
Fig. 5 Diagram of Mizoroki-Heck reaction
Fig. 6 Diagram of Pd@Co3O4 [31]
Fig. 7 Diagram of Aldol condensation reaction
Fig. 8 Diagram of A3-Coupling reaction
Fig. 9 Diagram of Au/MOF-199[44]
Fig. 10 Diagram of the ring-forming reaction of carbon dioxide and epoxy compounds
Fig. 11 Diagram of ZnO@NPC-Ox-700[51]
Fig. 12 Diagram of oxidation of unsaturated hydrocarbons
Fig. 13 Diagram of Zn1Co1-ZIF[55]
Fig. 14 Diagram of the reduction of unsaturated hydrocarbons
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