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Progress in Chemistry 2024, Vol. 36 Issue (2): 177-186 DOI: 10.7536/PC230613 Previous Articles   Next Articles

• 12 •

In-situ Preparation Methods of Hydrogen Peroxide via Water Oxdation

Jingze Yu1, Tengfeng Xie2()   

  1. 1 College of New Energy and Environment, Jilin University, Changchun 130021, China
    2 College of Chemistry, Jilin University, Changchun 130012, China
  • Received: Revised: Online: Published:
  • Contact: *e-mail: xietf@jlu.edu.cn
  • Supported by:
    National Natural Science Foundation of China(22172057)
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Hydrogen peroxide (H2O2) is an important chemical that may be used as a clean disinfectant. For scale application, H2O2 is produced primarily by the anthraquinone process. The necessary transportation and storage processes bring explosion risks, so it is urgent to develop in-situ preparation methods. Electrochemical and photocatalytic reduction of oxygen to product H2O2 have received wide attention, but these reactions are carried out at the gas-liquid-solid interface. This three-phase reaction requires complex equipment and sequentially limits large-scale production. Another equally important pathway for in-situ H2O2 production is the oxidation of water which needs only solid-liquid two-phase interface. This paper summarizes the common methods of oxidizing water to prepare H2O2, such as electrochemistry and photocatalysis, and focuses on the recent new methods of in-situ H2O2 preparation, including thermal catalysis, ultrasonic piezoelectricity, plasma and microdroplet method. These methods provide the references for in-situ H2O2 production and in particular its utilization in the field of disinfection.

Contents

1 Industrial process for the production of hydrogen peroxide

2 In-situ production of hydrogen peroxide via oxygen reduction reaction

3 In-situ production of hydrogen peroxide via water oxidation reaction

3.1 Electrochemical and photocatalytic hydrogen peroxide generation from water oxidation

3.2 Thermocatalytic hydrogen peroxide generation

3.3 Ultrasonic piezoelectrical hydrogen peroxide generation

3.4 Electrical discharge plasma hydrogen peroxide generation

3.5 Generation of hydrogen peroxide from aqueous microdroplets

4 Conclusion and outlook

Key words: disinfection, hydrogen peroxide, in-situ preparation, water oxidation
Fig.1 Schematic diagram of electrochemical reactor and reaction route for H2O2 production
Fig.2 Schematic diagram of photo- electrochemical reactor and reaction route for H2O2 production
Fig.3 Schematic diagram of ultrasonic-driven generation of H2O2 over g-C3N4
Table 1 Performance comparison of in-situ H2O2 preparation via water oxdation
Methods Typical H2O2 concentration(%) General yield (mL/min) Ref
electrochemicistry 0.04~0.1 ~2 1,32
photocatalysis
thermocatalysis ~0.1 0.05 49
piezoelectricity ≤0.01 ~1 54
plasma ~0.03 ~1 61
microdroplet ~0.1 unlimited 71,72
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