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Progress in Chemistry 2023, Vol. 35 Issue (9): 1304-1312 DOI: 10.7536/PC230213 Previous Articles   Next Articles

• Review •

Oxygen Permeability of Polymer Hydrogel Materials

Shiping Jin, Ying Sun, Xueqin Zhang()   

  1. College of Chemistry and Chemical Engineering, Southeast University,Nanjing 211189, China
  • Received: Revised: Online: Published:
  • Contact: *e-mail: xqzhang@seu.edu.cn
  • Supported by:
    The National Natural Science Foundation of China(22275035); Jiangsu Key Research and Development Program(BE 2022025-2)
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In recent years, hydrogels have been widely used in biomedical fields such as contact lenses and medical dressings. In these fields, oxygen permeability is a key index to evaluate the application performance of hydrogel materials. In this paper, the application of traditional hydrogels and silicone hydrogels in the field of corneal contact lenses and medical dressings is sketched. The research progress of traditional hydrogels and silicone hydrogels in structural design and oxygen permeability mechanism is summarized, and various factors affecting the oxygen permeability of silicone hydrogels are analyzed emphatically. It is hoped that the relationship between hydrogel microstructure and oxygen permeability can be further understood by summarizing and sorting out the recent related research work, so as to provide help for the regulation of material properties and the design of materials to meet the requirements.

Contents

1 Introduction

2 Progress in oxygen permeability of traditional hydrogels

2.1 Research progress of traditional hydrogels as contact lenses

2.2 Oxygen permeability mechanism of hydrogel materials

3 Progress in oxygen permeability of silicone hydrogels

3.1 Research progress of silicone hydrogels as contact lenses

3.2 Oxygen permeability mechanism of silicone hydrogel materials

4 Conclusion and outlook

Key words: polymer hydrogel, silicone hydrogel, oxygen permeability, oxygen permeability mechanism, microstructure
Fig.1 Relationship between Dk of hydrogel and water content[31]
Table 1 Summary of the work of traditional hydrogels and silicone hydrogels
Component Preparation method Oxygen permeability Water content ref
Traditional hydrogels HEMA、MPC Copolymerization 33 barrer 58% 17
HEMA、MA、MMA Ontology aggregation 35 barrer 45% 23
NVP、HEMA Copolymerization 35 barrer 84.5% 19
Silicone hydrogels KH570、HEMA、NVP Ontology aggregation 35 barrer / 43
SIGMA、HEMA、NVP Hydrate after
copolymerization		 34.5 barrer / 44
PDMS、PEGMA、HEMA Copolymerization 92 barrer / 48
PDMS、PTMO、HMDI Copolymerization 100 barrer / 49
PEG、PDMS Copolymerization 110 barrer / 18
PDMS、PEG、 Fluorohydrocarbon groups Copolymerization 196 barrer / 50
TEOS、PDMS、HEMA、NVP Photopolymerization 71 barrer 73% 52
Fig.2 Appearance of bulk material (grey) and open spaces (white) in the molecular structure of simulated pHEMA-based material (left) and Si-Hy material (right) at 37 wt% water content[58]. Copyright 2014, Elsevier
Fig.3 The relationship between Dk and silicon content and distribution and the possible forms of silica hydrogels[62]. Copyright 2017, Elsevier
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