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Progress in Chemistry 2023, Vol. 35 Issue (6): 928-939 DOI: 10.7536/PC221226 Previous Articles   Next Articles

• Review •

Strong Metal-Support Interactions of Metal/Meatal Oxide Catalysts

Xuetao Qin, Ziqiao Zhou, Ding Ma()   

  1. College of Chemistry and Molecular Engineering, Peking University,Beijing 100871, China
  • Revised: Online: Published:
  • Contact: *e-mail: dma@pku.edu.cn
  • Supported by:
    The National Natural Science Foundation of China(22102007); The National Natural Science Foundation of China(21991150); The National Natural Science Foundation of China(22172150); The National Natural Science Foundation of China(21821004); The National Natural Science Foundation of China(22072090)
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Catalysis plays an important role in the modern chemical industry, and developing catalyst with high efficiency is one of the important targets in catalysis research. Due to the outstanding activity of those catalysts with strong metal-support interactions (SMSI), SMSI has become an important scientific topic in catalysis research. The SMSI phenomenon involves the encapsulation of the metal nanoparticles (NPs) by support, resulting in the improved stabilization of NPs, and the different catalytic performances due to the new interaction between NPs and the support. Currently, a great number of catalysts with SMSI have been designed and partially applied, also there are considerable literatures focusing on SMSI of supported catalysts, especially those using metal oxide for support. However due to the complexity, the nature of SMSI and the catalytic mechanism of SMSI deserve further study, and the argument about the driving force of SMSI formation still exists. This review summarizes the recent progress, effect, and the regulation of SMSI, hopefully providing the understanding of SMSI from the perspective of condensed matter chemistry, and a new strategy of catalyst design.

Contents

1 Introduction

2 Research progress in SMSI

2.1 Research history of SMSI

2.2 New types of SMSI

3 Influence of SMSI on catalytic performance

3.1 Activity and stability enhancement

3.2 Selectivity tuning

4 Modulating of SMSI

4.1 Pre-treatment conditions

4.2 Supports

4.3 Metal nanoparticles

5 Conclusion and outlook

Key words: condensed matter chemistry, catalysis chemistry, catalysts, strong metal-support interactions
Fig.1 Research progress in SMSI
Fig.2 (a) WGS activities of model Pt/CeO2(111) catalysts as a function of admetal coverage[5]; (b) Calculated reaction path for the dissociation of adsorbed H2O on a ceria-supported Pt cluster[6]
Fig.3 (a) XANES spectra of Pt1/Co3O4, Pt1/CeO2, Pt1/ZrO2, and Pt1/graphene SACs as well as the Pt foil and PtO2 reference at the Pt L3-edge; (b) the corresponding K2-weighted Fourier transform spectra; (c) DRIFTS of CO chemisorption on Pt1/Co3O4, Pt1/CeO2, and Pt1/ZrO2 at the saturation coverage; (d) XPS spectra of Pt1/Co3O4, Pt1/CeO2, Pt1/ZrO2, Pt1/graphene, and PtO2 in the Pt 4f region[42]
Fig.4 Structure and catalytic behavior of SMSI and A-SMSI[8]
Fig.5 Reaction-induced strong metal-support interactions in Ni/h-BN catalyst[50]
Fig.6 Schematic illustration of the SMSI effect between Au overlayers and carbide supports[51]
Fig.7 (a) The coordination number (CN) of Ir—Ir and Ir—O shells (data, right axis) relative to catalytic selectivity (bars, left axis) with Ir/Ce catalysts with different Ir loadings; (b) Ir L3-edge EXAFS of the Ir/Ce-used catalysts; (c) XPS analysis of the Ir/Ce-used catalysts[60]
Fig.8 HRTEM images and EELS spectra. (A-F) HRTEM images of RR2Ti-fresh, RR2Ti-H200, RR2Ti-H300, RR2Ti-H400, RR2Ti-H500, and RR2Ti-(H500+O400); (G) EELS spectra of the RR2Ti-H500 sample[61]
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