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Progress in Chemistry 2023, Vol. 35 Issue (8): 1168-1176 DOI: 10.7536/PC221222 Previous Articles   Next Articles

• Review •

Design and Application of Chiral Plasmonic Core-Shell Nanostructures

Wenliang Liu, Yuqi Wang, Xiaohan Li, Xuanyu Zhang, Jiqian Wang()   

  1. State Key Laboratory of Heavy Oil Processing, Center for Bioengineering and Biotechnology, China University of Petroleum (East China),Qingdao 266580, China
  • Received: Revised: Online: Published:
  • Contact: *e-mail: jqwang@upc.edu.cn
  • Supported by:
    National Natural Science Foundation of China(22072181); Innovation Fund Project for Graduate Student of China University of Petroleum(23CX04031A); Fundamental Research Funds for the Central Universities.
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Chirality describes the geometrical feature of an object that cannot overlap with its mirror image and has been a crucial concept in chemistry and biology since the 19th century. With the development of nanotechnology, chiral plasmonic nanomaterials are becoming the research focuses for scientists to develop chiral functional materials due to the special chiral optical properties and good biocompatibility. However, the relatively weak chiral signals limit their applications. Chiral plasmonic core-shell nanostructures combine the chiral plasmonic properties and core-shell structures, which is an effective strategy to amplify chiral signals. In addition, the core-shell nanostructure integrates the properties of both internal and external materials to complement each other, which can further improve the physicochemical properties and enhance the performance in various fields. This paper summarizes the design strategies of chiral plasmonic core-shell nanostructures based on the spatial distribution of chiral molecules, and reviews their applications in the fields of ultrasensitive sensing and chiral catalysis. We analyze the existing problems and their possible solutions, and make an outlook on their future development.

Contents

1 Introduction

2 Design strategies for chiral plasmonic core-shell nanostructures

2.1 Chiral molecules distributed on the shell

2.2 Chiral molecules distributed on the core

2.3 Chiral molecules distributed in the core-shell gap

3 Application of chiral plasmonic core-shell nanostructures

3.1 Ultra-sensitive sensing

3.2 Chiral catalysis

4 Conclusion and outlook

Key words: chiral plasmonic nanostructures, core-shell structure, chiral catalysis, ultra-sensitive sensing
Fig.1 (a)Schematic diagram of Au@DNA modified Ag. (b)Schematic diagram of the preparation of Au@DNA modified Ag. (c)TEM image of Au@DNA modified Ag. (d)UV-vis absorption spectra of DNA and Au@DNA modified Ag. (e)CD spectra of DNA, Au@Ag, and Au@DNA modified Ag[38]
Fig.2 (a)Schematic diagram of DNA bridged Au@AgAu. (b)Schematic diagram of the preparation of DNA bridged Au@AgAu. (c)TEM images of DNA bridged Au@AgAu. (d)CD spectra of DNA bridged Au@AgAu[39]
Fig.3 (a)Schematic diagram of Au@cysteine modified Ag. (b)TEM images of Au@cysteine modified Ag(c)CD spectra of Au@cysteine modified Ag. (d~f)Chiral response signal amplification strategy for Au@cysteine modified Ag[43]
Fig.4 (a)Schematic diagram of chiral molecules modified Au@Ag. (b)Schematic diagram of the preparation of DNA modified Au@Ag.(c)TEM images of DNA modified Au@Ag[44]. (d)Schematic diagram of the preparation of cysteine modified Au@Ag.(e)TEM images of cysteine modified Au@Ag[45]
Fig.5 (a)Schematic diagram of cysteine modified Au@Ag. (b)TEM image of cysteine modified Au@Ag.(c)CD spectra of cysteine modified Au@Ag. (d~f)Chiral response signal amplification strategy for cysteine modified Au@Ag[46]
Fig.6 (a)Schematic diagram of penicillamine modified Au@AgAu. (b)TEM images of penicillamine modified Au@AgAu.(c)Schematic diagram of the preparation of penicillamine modified Au@AgAu[47]
Table 1 Spatial distribution of chiral molecules in chiral plasmonic core-shell nanostructures and their g factors
Spatial distribution of chiral molecules Materials g-factors ref
Chiral molecules
distributed on the
shell		 Au@DNA modified Ag 4.4×10-3 38
DNA bridged Au@AgAu 1.21×10-2 39
Au@cysteine modified Ag 1.45×10-3 43
Chiral molecules
distributed on the
core		 DNA modified Au@Ag 1.93×10-2 44
cysteine modified Au@Ag 1×10-2 45
cysteine modified Au@Ag 1.3×10-3 46
Chiral molecules
distributed in the
core-shell gap		 penicillamine modified Au@AgAu 2.1×10-2 47
Fig.7 (a)DNA bridged Au@AgAu for zeptomolar DNA detection and sensing[39] ;(b)penicillamine-modified Au@AgAu for Zn2+ detection and sensing in living cells[47]
Fig.8 Cysteine modified Au@Ag for asymmetric catalysis[45]
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