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Progress in Chemistry 2023, Vol. 35 Issue (3): 349-359 DOI: 10.7536/PC220936   Next Articles

• Review •

Covalent Organic Frameworks for Photocatalytic CO2 Reduction

Liu Yvfei, Zhang Mi, Lu Meng(), Lan Yaqian()   

  1. School of Chemistry, South China Normal University, Guangzhou 510631, China
  • Received: Revised: Online: Published:
  • Contact: *menglu@m.scnu.edu.cn(Meng Lu); yqlan@m.scnu.edu.cn(Ya-Qian Lan)
  • Supported by:
    National Natural Science Foundation of China(21871141); National Natural Science Foundation of China(21871142); National Natural Science Foundation of China(22071109); National Natural Science Foundation of China(21901122); National Natural Science Foundation of China(22105080); National Natural Science Foundation of China(22201083); China Postdoctoral Science Foundation(2020M682747); China Postdoctoral Science Foundation(2021M701270); Guangdong Basic and Applied Basic Research Foundation(2023A1515010779); Guangdong Basic and Applied Basic Research Foundation(2023A1515010928)
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With the massive global consumption of fossil fuels, the energy crisis is getting worse and the emission of greenhouse gases such as CO2 has made the environmental problems become increasingly prominent. Photocatalytic reduction of CO2 to energy compounds is considered to be one of the best ways to effectively solve this problem. Covalent organic frameworks (COFs) are a new type of crystalline porous organic polymer materials with high stability and pre-design ability, which makes COFs own great potential ability in the field of photocatalytic CO2 reduction. This paper summarizes the research progress of COFs in the field of photocatalytic CO2 reduction, including the introduction of different metal ions to provide the active site and increasing the photosensitive functional groups to improve their utilization of visible light. Since the research of COFs as photocatalytic CO2 reduction catalyst is still an initial field, further exploration of synthesis, modification, and mechanism of COFs for CO2 reduction is still promising research work.

Contents

1 Introduction

2 Covalent organic frameworks

2.1 Basic information of COFs

2.2 Application of COFs in photocatalysis

3 Basic principles of photocatalytic CO2 reduction

4 COFs for photocatalytic CO2 reduction

5 Conclusion and outlook

Key words: covalent organic frameworks, photocatalysis, CO2 reduction, artificial photosynthesis
Fig. 1 (a) Schematic of topology of typical 2D COFs material; (b) Schematic of topology of typical 3D COFs material
Fig.2 Schematic diagram of the CO2 photoreduction mechanism based on the semiconductor band theory [5]
Fig. 3 (a) synthesis of COF and Re-COF; (b) side view of crystal; (c) AA overlapping stacked COF units; (d) CO2 reduction mechanism [21]
Fig. 4 Synthesis and metal coordination process of DQTP COF and DATP COF and its structure [22]
Fig. 5 Synthesis and structure of the COF-367 NSs[9]
Fig. 6 (a) DFT-calculated and related Gibbs free energy profiles for the CO2 reduction reaction. (b) Reaction mechanism for the photoconversion of CO2 into CO on Ni-TpBpy[24]
Fig. 7 (a) Schematic depiction for the synthesis of MP-TPE-COF; (b) PXRD patterns of NiP-TPE-COF; (c) top and side views for AA-stacking mode of NiP-TPE-COF (color online)[25]
Fig. 8 (a) Schematic representation of the mechanism of TTCOF-MCO2RR with water oxidation;(b) UV-vis DRS theoretical simulations of TTCOF-Zn and PET paths under light excitation[26]
Fig. 9 Schematic representation of the inorganic semiconductor-crystalline COFs Z-Scheme materials for artificial photosynthesis[27]
Fig.10 Structure of COF-POM material and its application in CO2 reduction[28]
Fig.11 Structure of Co-Py-CON material and its application in CO2 reduction[29]
Fig. 12 Synthesis and photocatalytic applications of COF-367-Co with different spin states of Co[31]
Fig. 13 (a) Schematic representation of the synthesis of CT-COF; (b) Time courses of photocatalytic activity for CO production[32]
Fig. 14 Photocatalytic application of the MOF@COF heterojunction catalysts with different morphologies [33]
Fig. 15 Schematic diagram of the synthesis and photocatalytic application of PdIn@N3-COF[34]
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