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Progress in Chemistry 2022, Vol. 34 Issue (5): 1181-1190 DOI: 10.7536/PC210449 Previous Articles   Next Articles

• Review •

Preparation and Application of Graphene/Metal-Organic Frameworks Composites

Yaoyu Qiao, Xuehui Zhang, Xiaozhu Zhao, Chao Li, Naipu He()   

  1. Research Institute, School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University,Lanzhou 730070, China
  • Received: Revised: Online: Published:
  • Contact: Naipu He
  • Supported by:
    Science and Technology Programs of Gansu Province(20YF8GA032)
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Metal-organic frameworks (MOFs), a novel class of crystalline materials with the ordered porous network frameworks, are formed by the coordination of metal ions and organic bridging ligands. Because of special and unique features such as the large surface area, tunable structure and high porosity, MOFs have attracted a lot of attention in materials, environment, biomedicine and so on. However, MOFs have some disadvantages including of being easily hydrolyzed, low stability, and low electrical conductivity. It is an ideal strategy that MOFs combined with other materials to improve their features and performances. In particular, graphene shows outstanding chemical stability, good electrical conductivity, optical properties and mechanical properties. Graphene compositing with MOFs can effectively improve the photoelectric properties, stability and recyclability of MOFs. Hence, in the current paper, preparation methods of graphene/MOFs composites, including in situ growth method, interfacial growth method and blending molding method, are reviewed. We also discuss their superior performance in the fields of gas separation and storage, water purification, chemical sensors, and catalysts. Moreover, the preparation development and potential applications of graphene/MOFs composites are proposed.

Contents

1 Introduction

2 Preparation methods of graphene/MOFs composite materials

2.1 In situ growth method

2.2 Interfacial growth method

2.3 Blending molding method

3 Applications of graphene/MOFs composite materials

3.1 Gas adsorption and storage

3.2 Water purification

3.3 Chemical sensor

3.4 Catalyst

4 Conclusions and outlook

Key words: graphene, metal-organic frameworks, composite materials, adsorption, sensor, catalyst
Fig. 1 Preparation of Ni-MOFs@GO nanosheets by the step-by-step method[25]. Copyright 2016, ACS
Fig. 2 Preparation of graphene/ZIF-8 hybrid aerogels by the step-by-step method[28]. Copyright 2018, ACS
Fig. 3 Preparation of SGO@HKUST-1 composite material by one-pot method[31]. Copyright 2016, ACS
Fig. 4 Preparation of Cu3(BTC)2/GO composite material by interfacial growth method[35]. Copyright 2015, ACS
Fig. 5 Adsorption and separation of gases using MOFs[39]. Copyright 2021, ACS
Fig. 6 Nitrobenzene recognition based on an MOF Sensor[65]. Copyright 2021, ACS
Fig. 7 A schematic diagram of the synthesis process of Ni-MOF-74/G[71]. Copyright 2018, ACS
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