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Progress in Chemistry 2021, Vol. 33 Issue (12): 2404-2412 DOI: 10.7536/PC210103 Previous Articles   

• Review •

Synthesis, Modification of Bismuth Oxyiodide Photocatalyst for Purification of Nitric Oxide

Hanqiang Zhou1, Mingfei Yu1, Qiaoshan Chen1(), Jianchun Wang2(), Jinhong Bi1()   

  1. 1 College of Environment and Resources, Fuzhou University,Fuzhou 350108, China
    2 Fujian Longking Co. Ltd,Xiamen 361000, China
  • Received: Revised: Online: Published:
  • Contact: Qiaoshan Chen, Jianchun Wang, Jinhong Bi
  • Supported by:
    the National Natural Science Foundation of China(5167204); the Natural Science Foundation of Fujian Province(2019J01648)
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Photocatalytic technology has shown great potential for purification of low-concentration nitric oxide (NO) pollution due to its energy-saving property, high efficiency, and limited secondary pollution. Among various semiconductors, bismuth oxyiodide (BiOI) photocatalyst has drawn considerable attention in recent years due to the superior photocatalytic activity and stability, since its narrow band gap and specific layered structure is in favor of visible light absorption and electron-hole pairs separation. Hence, we overview the latest research progress in the photocatalytic purification of NO by BiOI and introduce the influence of crystalline morphology and facets on its photocatalytic performance. The modification and activity enhancement mechanism of BiOI is emphatically expounded, for example, surface modification, ion doping and heterostructure construction. The future prospects and challenges in this research spot are put forward for the sake of providing theoretical reference and technical support for the design of highly active BiOI and the efficient purification of low concentration NO.

Contents

1 Introduction

2 Reaction mechanism and pathway of photocatalytic purification of NO

3 Controlled synthesis of bismuth oxyiodide

3.1 Morphological control

3.2 Crystal plane control

4 Surface modification and ion doping of bismuth oxyiodide

5 Construction of bismuth oxyiodide heterojunction

5.1 Bismuth oxyiodide/semiconductor heterojunction

5.2 Bismuth oxyiodide/insulator heterojunction

5.3 Ternary heterojunction

6 Conclusion and outlook

Key words: bismuth oxyiodide, nitric oxide, photocatalysis, atmospheric contamination
Fig.1 Numbers of annually published articles on photocatalytic NO purification in recent ten years (Source: Web of Science)
Fig.2 (a)Crystal structure of BiOI and (b) the schematic illustration of photocatalytic purification of NO based upon BiOI under visible light
Fig.3 (a~c)SEM images of as-synthesized BiOI spheres and (d~f) plates[37]. Copyright 2019, IOP Publishing Ltd
Table 1 Removal efficiency of NO by surface modification and ion-doped modification of BiOI
Catalyst Modified element Dosage Light source Concentration and time Photocatalytic activity ref
BiOI Bi 0.1 g 150 W halogen tungsten lamp,λ > 420 nm 600 ppb, 30 min 40.8% 47
BiOI Bi 0.2 g 150 W lamp, λ > 420 nm ppb levels, 30 min 51.4% 48
BiOI Bi 0.05 g 500 W Xe lamp 500 ppb, 1 h 46.5% 49
Bi5O7I Er 0.1 g 300 W Xe lamp 450 ppb, 30 min 54.0% 50
BiOI Zn 0.1 g 300 W Xe lamp, λ > 420 nm 430 ppb, 30 min 53.6% 42
Bi5O7I La
Au
La、Au		 / 300 W Xe lamp, λ > 420 nm 400 ppb, 30 min 42.7%
34.2%
52.5%		 51
Fig.4 Schematic illustration of the photo-oxidative removal of NO by 3%Zn-BiOI in the dark and under visible light irradiation[42]. Copyright 2019, American Chemical Society
Fig.5 Schematic representation of NO photooxidation mechanism on the surface of Bi2WO6/BiOI vertical heterostructure[54]. Copyright 2019, Wiley
Table 2 Removal efficiency for NO by BiOI heterojunction
Catalyst Dosage Light source Concentration and time Photocatalytic activity Ref
BiOI/BiOCl 0.15 g 300 W halogen tungsten lamp, λ > 400 nm 450 ppb, 30 min 54.6% 53
BiOBr/BiOI 0.15 g Xe lamp, λ > 420 nm 600 ppb, 50 min 57% 28
Bi2WO6/BiOI 0.2 g 150 W Xe lamp, λ > 420 nm 500 ppb, 30 min 40% 54
Bi2O2CO3/BiOI 0.2 g 150 W halogen tungsten lamp, λ > 420 nm 600 ppb, 30 min 50.8% 55
BiOIO3/BiOI 0.1 g 150 W halogen tungsten lamp, λ > 420 nm 550 ppb, 30 min 41.3% 56
BiOI/La(OH)3 0.1 g 150 W halogen tungsten lamp, λ > 420 nm 520 ppb, 30 min 50.5% 57
SrTiO3/BiOI 0.2 g λ > 420 nm ppb levels, 30 min 59% 58
BiOI/ZnWO4 0.1 g 300 W Xe lamp, λ > 420 nm 430 ppb, 30 min 48.24% 59
SrCO3/BiOI 0.2 g λ > 420 nm ppb levels, 30 min 48.3% 27
BaCO3/BiOI 0.2 g λ > 420 nm ppb levels, 30 min 47.5% 60
CaSO4/BiOI 0.2 g λ > 420 nm ppb levels, 30 min 54.4% 61
BiOBr0.5I0.5/BiOBr/BiOI 0.15 g Xe lamp, λ > 420 nm 750 ppb, 15 min 48% 62
Bi/BiOI/Bi2O2CO3 0.2 g 150 W halogen tungsten lamp, λ > 420 nm 550 ppb, 30 min 50.7% 63
Bi/BiOI/graphene 0.1 g 300 W Xe lamp, λ > 420 nm 430 ppb, 30 min 51.8% 64
Fig.6 The side view of the (001) plane of BiOI and the (010) plane of BiOIO3 (a) and the schematic diagram of BiOI grown on the (010) facets of BiOIO3 (b)[56]. Copyright 2015, Royal Society of Chemistry
Fig.7 Schematic diagram for the separation and transfer of photogenerated carriers and the photocatalytic process over the insulator-semiconductor heterojunction[60]. Copyright 2018, Royal Society of Chemistry
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