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Progress in Chemistry 2021, Vol. 33 Issue (11): 1964-1971 DOI: 10.7536/PC201062 Previous Articles   Next Articles

Special Issue: 金属有机框架材料

• Review •

Preparation and Application of MOFs/ Hydrogel Composites

Chao Li1, Yaoyu Qiao1, Yuhong Li1, Jing Wen1, Naipu He1,2(), Baiyu Li1   

  1. 1 School of Chemical and Biological Engineering, Lanzhou Jiaotong University,Lanzhou 730070, China
    2 Research Institute, Lanzhou Jiaotong University,Lanzhou 730070, China
  • Received: Revised: Online: Published:
  • Contact: Naipu He
  • Supported by:
    National Natural Science Foundation of China(51963014)
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Metal-organic frameworks(MOFs) have a large number of pore structures and active sites, which enable them to play a huge role in gas adsorption, catalysis, medical treatment and other fields. As a crystal powder, MOFs are brittleness, easy hydroxylation, difficulty in recycling and so on which limits its application. MOFs combining to flexible polymers, in particular combining to hydrogels greatly improve the flexibility, dispersibility in water, recyclability, and processability of composite materials, which broadens the application fields of MOFs. In the present paper, it is elaborated that the progress of the preparation of MOFs/hydrogel composites are based on three different methods including MOFs in situ growing from hydrogel, MOFs/hydrogel simultaneous generation, and hydrogel encapsulated MOFs. The characteristics of the above three preparation methods and their resulting product properties are summarized. Additionally, the applications of composite materials in biomedicine, catalysis, wastewater treatment, and gas adsorption are further summarized. Finally, preparation method improvement and future application of MOFs/ hydrogel composites are discussed and prospected.

Contents

1 Introduction

2 Preparation of MOFs/hydrogel composites

2.1 MOFs in situ growing from hydrogel

2.2 MOFs/hydrogel simultaneous generation

2.3 Hydrogel encapsulated MOFs

3 Application of MOFs/hydrogel composites

3.1 Biomedical applications

3.2 Catalysis

3.3 Wastewater treatment

3.4 CO2 adsorption

4 Conclusion and outlook

Key words: MOFs, hydrogel, composite material, medical treatment, catalysis, wastewater treatment, gas adsorption
Fig. 1 MOFs/hydrogel preparation process(A): MOFs in situ growing from hydrogel (B): MOFs/hydrogel simultaneous generation (C): Hydrogel encapsulated MOFs
Fig. 2 (A) Schematic of the preparation of MOF-alginate composite; Photographs of(B) alginate hydrogels cross-linked by Cu2+ right after the addition of sodium alginate aqueous solution into Cu2+ aqueous solution;(C) alginate hydrogels cross-linked by Cu2+ after washed with water and ethanol; and(D) HKUST-1-alginate hydrogels[27]
Fig. 3 Schematics of the chemical composition and 3D printing process for the MOF hydrogel structures.(A) Composition of the hydrogel precursor ink(left), UV-cured hydrogel matrix(middle), and the HKUST-1 hydrogel(right);(B) Schematic showing the three critical steps in the 3D printing process including printing, UV curing, and ionic cross-linking[31]
Fig. 4 Preparation of HKUST-1 and hybrid hydrogel[36]
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