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Progress in Chemistry 2021, Vol. 33 Issue (10): 1731-1740 DOI: 10.7536/PC200904 Previous Articles   Next Articles

• Review •

Preparation and Application of Lead Halide Perovskite-Polymer Composites

Jingjing Xiao1,2, Mu Wang3, Weijie Zhang1,2, Xiuying Zhao1,2(), Anchao Feng1,2(), Liqun Zhang1,2   

  1. 1 Beijing Key Laboratory of Preparation and Processing of New Polymer Materials, Beijing University of Chemical Technology,Beijing 100029, China
    2 School of Materials Science and Engineering, Center of Advanced Elastomer Materials, Beijing University of Chemical Technology,Beijing 100029, China
    3 Sinopec Research Institute of Petroleum Engineering,Beijing 100101, China
  • Received: Revised: Online: Published:
  • Contact: Xiuying Zhao, Anchao Feng
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With excellent photoelectric properties, lead halide perovskite nanocrystals(NCs) show great potential in solar cells, photoelectric detection, biological imaging and other fields. However, the poor stability of lead halide perovskite NCs restricts practical applications. Within a few years, many strategies have been developed to solve the problems of poor stability of perovskite NCs, such as ion doping, surface passivation and surface cladding. Noteworthily, it is an effective strategy developed recently that enhance the stability of perovskite by embedding perovskite NCs into polymer and preparing perovskite-polymer composites. Specially, the dense polymer matrix endows the lead halide perovskite NCs with excellent water stability. This review summarizes the preparation of perovskite-polymer composites and their applications in the fields of light-emitting devices and biomedicine. At the same time, the preparation methods of perovskite-polymer composites are discussed in details, which can be classified into three types: blending, in-situ polymerization and in-situ perovskite growth/precipitation method. These methods will be a guide to overcome the limitation of perovskite NCs and impel the development of their practical application. In addition, the existing problems for encapsulating perovskite NCs into polymer matrix are highlighted, while some suggestions for further improving the performance of perovskite-polymer composites are discussed. Finally, the future development of perovskite-polymer composites is prospected.

Contents

1 Introduction

2 Preparation of lead halide perovskite-polymer composites

2.1 Blending method

2.2 In situ polymerization method

2.3 In situ perovskite growth/ precipitation method

3 Application of lead halide perovskite-polymer composites

4 Conclusion and outlooks

Key words: lead halide perovskite, nanocrystals(NCs), polymer, composites, light-emitting devices, biomedical
Fig. 1 Crystal structures of lead halide perovskites
Fig.2 (a) Schematic of CsPbX3@SBS fiber membranes(FMs) fabrication process.(b) Optical image of red, yellow, green, and blue composite FMs under UV-light excitation.(c) Fluorescence microscopic images of versatile CsPbX3 fibers[52]
Fig.3 Schematic diagram of the electrospraying method for preparing CsPbBr3@PS microspheres[42]
Fig. 4 Preparation process of perovskite-polymer composites(CsPbBr3-polymer or CH3NH3PbBr3-polymer)[43]
Fig. 5 Proposed reaction mechanism of the perovskite photoactivated polymerization of styrene[56]
Fig.6 (a) Preparation of MAPbBr3 polymer composite films.(b) Water stability tests of MAPbBr3 polymer composite films.(c) Thermal stability tests of MAPbBr3 polymer composite films.[45]
Fig.7 (a) Illustration of the Synthesis of Ternary NC-GO-g-PAA Hybrid.(b)TEM images of the NC-GO-g-PAA hybrid and self-assembled nanorods.(c) Photographs of glass slides coated with NC-GO-g-PAA nanorod films after soaking in water or exposure to air for 0 and 10 days[67]
Fig.8 (a) Schematic diagram of the configuration of the prototype LED device and photographs of white LED;(b) Emission spectrum of the white LED;(c) A demonstration of composite films based backlight system with a size of 3.5 cm × 5 cm.(d) The color coordinate(black star) and the color triangle(white line) of obtained white LED is exhibited in CIE 1931 diagram[58]
Fig.9 (a, b, c-1) and(-2) Bright-field and fluorescence images of RAW 264.7 cells incubated with CsPbX3 NCs@MHSs.(a, b, c-3) Overlaid picture of(-1) and(-2).(d~f)The PL spectra of intracellular CsPbX3[69]
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