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Progress in Chemistry 2021, Vol. 33 Issue (6): 942-957 DOI: 10.7536/PC200869 Previous Articles   Next Articles

• Review •

Reactive Fluorescent Probe for Hypochlorite

Chunping Ren, Wen Nie, Junqiang Leng, Zhenbo Liu*()   

  1. College of Chemistry and Chemical Engineering, Yantai University,Yantai 264005, China
  • Received: Revised: Online: Published:
  • Contact: Zhenbo Liu
  • About author:
    * Corresponding author e-mail:
  • Supported by:
    Natural Science Foundation of Shandong Province(ZR2019QB017); Scientific and Technological Innovation Fund for Postgraduates of Yantai University in 2020(YDYB2010)
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Hypochlorous acid in organisms is produced from the reaction between chloride ions and hydrogen peroxide(H2O2) catalyzed by myeloperoxidase(MPO). It is one of the most important reactive oxygen species(ROS) in organisms and plays a vital role in physiological processes. However, excessive hypochlorite can lead to a series of physiological diseases, so the effective identification and detection of hypochlorite is favored by researchers. Compared with traditional detection methods, fluorescent probes have many advantages, such as good selectivity, high sensitivity and real-time monitoring, so they have been developed rapidly in recent years. In this paper, based on different fluorophores, the research progress and biological application of hypochlorite fluorescent probes in the last three years are reviewed.

Contents

1 Introduction

2 Hypochlorite fluorescent probes based on different fluorophores

2.1 BODIPY based HClO fluorescent probes

2.2 Fluorescein based HClO fluorescent probes

2.3 Rhodamine based HClO fluorescent probes

2.4 Coumarin based HClO fluorescent probes

2.5 Cyanine based HClO fluorescent probes

2.6 Benzothiazole based HClO fluorescent probes

2.7 Naphthalene dimethylimide based HClO fluorescent probes

2.8 Other HClO fluorescent probe

3 Conclusions and outlook

Key words: hypochlorous acid, fluorescent probe, recognition, detection
Fig.1 Structure of BODIPY
Fig.2 Reaction mechanism of probe 1 for HClO and cell imaging[35]
Fig.3 Reaction mechanism of probe 2 for ClO- [36]
Fig.4 Reaction mechanism of probe 3 for HClO[37]
Fig.5 Reaction mechanism of probe 4 for HClO[38]
Fig.6 Reaction mechanism of probe 5 for HClO[39]
Fig.7 Reaction mechanism of probes 6,7,8 for HClO[40]
Fig.8 Reaction mechanism of probe 9 for HClO[41]
Fig.9 Reaction mechanism of probe 10 for ClO-[42]
Fig.10 Structure of fluorescein
Fig.11 Reaction mechanism of probe 11 for HClO[43]
Fig.12 Reaction mechanism of probe 12 for ClO-[44]
Fig.13 Structure of Rhodamine B(left) and Rhodamine 6G(right)
Fig.14 Reaction mechanism of probe 13 for HClO[45]
Fig.15 Reaction mechanism of probe 14 for HClO[46]
Fig.16 Reaction mechanism of probe 15 for HClO[47]
Fig.17 Reaction mechanism of probe 16 for HClO and cell imaging[48]
Fig.18 Reaction mechanism of probe 17 for HClO and cell imaging[49]
Fig.19 Reaction mechanism of probe 18 for HClO[50]
Fig.20 Structure of coumarin
Fig.21 Reaction mechanism of probe 19 for HClO[51]
Fig.22 Reaction mechanism of probe 20 for HClO/ClO-[52]
Fig.23 Reaction mechanism of probe 21 for HClO/ClO-[53]
Fig.24 Reaction mechanism of probe 22 for HClO and cell imaging[54]
Fig.25 Reaction mechanism of probe 23 for HClO[55]
Fig.26 Structure of cyanine dye
Fig.27 Reaction mechanism of probe 24 for NaClO[56]
Fig.28 Reaction mechanism of probe 25 for NaClO[21]
Fig.29 Reaction mechanism of probe 26 for HClO[57]
Fig.30 Structure of benzothiazole
Fig.31 Reaction mechanism of probe 27 for ClO-[62]
Fig.32 Reaction mechanism of probe 28 for HClO[63]
Fig.33 Reaction mechanism of probe 29 for HClO[64]
Fig.34 Reaction mechanism of probe 30 for HClO/ClO-[18]
Fig.35 Reaction mechanism of probe 31 for HClO/ClO-[65]
Fig.36 Structure of 1,8-naphthalimide derivatives
Fig.37 Reaction mechanism of probe 32 for HClO[66]
Fig.38 Reaction mechanism of probe 33 for HClO and cell imaging[67]
Fig.39 Reaction mechanism of probe 34 for HClO and zebrafish imaging[68]
Fig.40 Reaction mechanism of probe 35 for NaClO[69]
Fig.41 Reaction mechanism of probe 36 for HClO and zebrafish imaging[70]
Fig.42 Reaction mechanism of probe 37 for HClO and cell imaging[71]
Fig.43 Reaction mechanism of probes 38 and 39 for HClO[72]
Fig.44 Reaction mechanism of probe 40 for HClO and zebrafish imaging[73]
Fig.45 Reaction mechanism of probe 41 for HClO/ClO- [74]
Fig.46 Reaction mechanism of probe 42 for HClO and mice imaging[75]
Fig.47 Reaction mechanism of probe 43 and 44 for ClO-[76]
Fig.48 Reaction mechanism of probe 45 for HClO[77]
Fig.49 Reaction mechanism of probe 46 for ClO-[78]
Fig.50 Reaction mechanism of probe 47 for HClO and zebrafish imaging[79]
Fig.51 Reaction mechanism of probe 48 for HClO[33]
Fig.52 Reaction mechanism of probe 49 for ClO-[80]
Fig.53 Reaction mechanism of probe 50 for HClO[81]
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