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Progress in Chemistry 2021, Vol. 33 Issue (11): 1953-1963 DOI: 10.7536/PC200856 Previous Articles   Next Articles

• Review •

Preparation of SiO2/Polymer Nanocomposites Based on Polymerization-Induced Self-Assembly

Yena Feng1,2, Shuhe Liu2, Shubo Zhang2, Tong Xue2, Honglin Zhuang2, Anchao Feng1,2()   

  1. 1 Beijing Key Laboratory of Preparation and Processing of New Polymer Materials, Beijing University of Chemical Technology,Beijing 100029, China
    2 Center of Advanced Elastomer Materials, College of Materials Science and Engineering, Beijing University of Chemical Technology,Beijing 100029, China
  • Received: Revised: Online: Published:
  • Contact: Anchao Feng
  • Supported by:
    National Natural Science Foundation of China(21704001); SINOPEC(H2019485)
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Nano-silica(SiO2) particles are widely used in the preparation of composite materials due to their high hardness, high specific surface area, high stability and reasonable price. The obtained SiO2/polymer composite materials generally have excellent mechanical properties, good thermal stability, enhanced optical and electrical properties. In recent years, with the development of polymerization-induced self-assembly(PISA), scientists have developed a variety of simple methods for preparing polymeric nanoparticles with different morphologies based on PISA, which provides a new way to prepare SiO2/polymer composites. Although there are many related reviews of SiO2/polymer composites, while there is no review on the preparation of nanocomposites based on PISA. Thus we investigated the relevant research in the past ten years on the preparation of SiO2/polymer composite materials based on PISA. According to the different interaction between SiO2 and polymer and the compound mechanism, the preparation of SiO2/polymer composite materials was innovatively divided into physical encapsulation method, chemical grafting method, supramolecular interaction method and in-situ growth method. This review focuses on the synthesis methods, main properties and applications of composite materials, while analyzes the advantages and disadvantages of various composite methods and makes prospects for the future development of preparation methods. It is hoped to provide a clearer context and richer information for scientific researchers in related fields.

Contents

1 Introduction

2 Physical encapsulation

3 Chemical grafting

3.1 Grafting to

3.2 Grafting from

4 Supramolecular interaction

4.1 Hydrogen bond interaction

4.2 Electrostatic interaction

5 In-situ growth

6 Conclusions and outlooks

Key words: polymerization induced self-assembly(PISA), SiO2, polymeric nanocomposites, supramolecular interaction, in-situ growth
Fig. 1 One-pot preparation of composite polymer electrolyte[10]
Fig. 2 Photo-initiated preparation of polymer assemblies[11]
Fig. 3 Copolymer vesicles(1a), vesicles encapsulating SiO2 nanoparticles(1b), pure SiO2 nanoparticles(1c), TEM images after cooling treatment at different temperature(2a~d)[13]
Fig. 4 Schematic diagram(a), TEM images(b), AFM images and corresponding water contact angle(c) of PTFEMA/SiO2 composite latex[20]
Fig. 5 Schematic diagram of SiO2 grafted polymer composite vesicles[26]
Fig. 6 Change of polymer morphology on the surface of SiO2 nanoparticles[28]
Fig. 7 Schematic and electron micrograph of multi-pod SiO2/polymer composite latex particles[35]
Fig. 8 (a,b) TEM and FESEM images of SiO2/PAM core-shell nanoparticles;(c) schematic diagram of SiO2/PMAC composite particles prepared by electrostatic adsorption[41]
Fig. 9 (a) Schematic diagram of silicon shell growth(through TEOS hydrolysis and condensation);(b) volume distribution of DLS before and after the growth of silica shell;(c~f) TEM and SEM images of particles after silicon shell growth[49]
Table 1 The comparison of four synthesis methods
synthesis method morphologies advantages disadvantages
physical encapsulation vesicle[10⇓⇓~13] simple and readily prepared in large quantities non-rigid performance requirements
chemical grafting sphere[20,25],vesicle[26],
nanowire[27]		 firm Chemical bonding and stable performance harsh reaction conditions and low graft efficiency
supramolecular interaction raspberry shape[35],
core-shell[37,41,42],snowman shape[37],sphere[39]		 simple method low bonding strength
in-situ growth core-shell[49,51],nanowire[50],
raspberry shape[51]		 simple and readily prepared in large quantities harsh reaction conditions and low bonding strength
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