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Progress in Chemistry 2021, Vol. 33 Issue (8): 1404-1413 DOI: 10.7536/PC200764 Previous Articles   Next Articles

Special Issue: 锂离子电池

• Review •

Investigation of Electrode Materials for Lithium Ion Capacitor Battery

Kedi Cai1, Shuang Yan1, Tianye Xu1, Xiaoshi Lang1,2(), Zhenhua Wang3()   

  1. 1 College of Chemistry and Materials Engineering, Bohai University,Jinzhou 121013, China
    2 Liaoning Engineering Technology Research Center of Supercapacitor,Jinzhou 121013, China
    3 College of Chemistry and Chemical Engineering, Beijing Institute of Technology,Beijing 100081, China
  • Received: Revised: Online: Published:
  • Contact: Xiaoshi Lang, Zhenhua Wang
  • Supported by:
    National Natural Science Foundation of China(22075030)
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With the advantages of both lithium ion battery and supercapacitor, lithium ion capacitor battery has become a promising new energy storage system with its advantages of high energy density, high power density, long cycle life and fast charging and discharging. However, some key problems still exist, such as dynamic imbalance, less ideal energy density and poor cycling stability between battery electrode and capacitor electrode. The electrode material is an important part of the battery and seriously affects the overall electrochemical performance. To solve this problem effectively, a variety of new type of anode and cathode electrode materials should be developed in this field. Therefore, this paper introduces in detail the research progress and technical route of cathode(layered metal oxides, graphene composite anode and other novel cathode materials) and anode(transition metal oxides, carbon materials, lithium compounds and sulfides) materials for lithium ion capacitor batteries, and analyzes the existing problems. It is found that the properties of electrode materials can be improved by nano treatment, material coating and heteroatomic doping. At the same time, the future research direction of electrode materials is prospected, and new ideas and means are provided for the research of other chemical power sources.

Contents

1 Introduction

2 Anode materials

2.1 Transition metal oxide

2.2 Carbon materials

2.3 Lithium compound

2.4 Sulfide

3 Cathode materials

3.1 Layered metal oxide

3.2 Graphene composite cathode

3.3 Other new cathode materials

4 Conclusion and outlook

Key words: lithium ion capacitor battery, anode material, cathode material, composite, performance
Fig. 1 Diagram of advantages of Li-ion capacitor batteries
Fig. 2 Synthesis of MoS2/NC composite material[37]
Fig. 3 Preparation process of Li1.2Mn0.56Ni0.16Co0.08O2[46]
Fig. 4 (a) Synthesis of LiNi0.88Co0.095Mn0.025O2@Al composite material,(b) cycle capability at 1 C rate,(c) rate capability under different C-rates[47].
Fig. 5 (a) Schematic diagram of the synthesis of rGO/V2O5,(b) SEM images of V2O5 nanoparticles anchored on rGO nanosheets after annealing in vacuum at 300 ℃ for 2 h,(c) The rate performance at various rates from C/9 to 10 C[56].
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