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Progress in Chemistry 2021, Vol. 33 Issue (8): 1450-1460 DOI: 10.7536/PC200748 Previous Articles   

• Review •

Inner Filter Effect for Environmental Monitoring

Yong Xie1,2, Mingjie Han1,2, Yuhao Xu1,2, Chenyu Xiong1,2, Ri Wang1,2, Shanhong Xia1()   

  1. 1 State Key Laboratory of Transducer Technology, Aerospace Information Research Institute, Chinese Academy of Sciences,Beijing 100094, China
    2 School of Electronic, Electrical and Communication Engineering, University of Chinese Academy of Sciences,Beijing 100049, China
  • Received: Revised: Online: Published:
  • Contact: Shanhong Xia
  • Supported by:
    National Basic Research Program of China(2015CB352100)
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Inner filter effect(IFE) refers to the phenomenon that the absorber absorbs the excitation and/or emission light of the fluorophore, resulting in the fluorescence quenching of the fluorophore. Compared with fluorescence resonance energy transfer(FRET) or other techniques, IFE avoids cumbersome labeling processes, and has the advantages of high sensitivity, strong selectivity, simple and flexible operation. The IFE-based fluorescent approach has broad application foreground in the field of environmental monitoring. The absorber and the fluorophore are the two main components of the IFE-based sensing system. The optical properties and the spectral overlap of the two directly affect the quenching efficiency of the IFE-based sensing system. There are relatively limited choices of materials for the absorber and the fluorophore. Discovering new nanomaterials and exploring suitable absorber/fluorophore pair are very helpful to improve the quenching efficiency of IFE and enhance the detection performance of the IFE-based fluorescent approach. In this review, we mainly focus on the recent progress of IFE researches for environmental monitoring, including the detection of heavy metal ions, anions and small molecular environmental pollutants. The important effects of nanomaterials in the IFE-based sensing system are analyzed. Finally, the challenges and future developments of the IFE-based fluorescent approach are discussed.

Contents

1 Introduction

2 IFE applied to environmental monitoring

2.1 Detection of heavy metal ions

2.2 Detection of anions

2.3 Detection of small molecule environmental pollutants

3 Conclusion and outlook

Key words: inner filter effect(IFE), environmental monitoring, nanomaterials, heavy metal ions, anions, pesticides, small molecule environmental pollutants
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