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Progress in Chemistry 2020, Vol. 32 Issue (12): 1879-1884 DOI: 10.7536/PC200408 Previous Articles   Next Articles

• Review •

Synthesis and Properties of H-Shaped Polymers

Yang Bai1,**(), Xiaochen Yan1, Caiping Liu1, Hao Yao2,**()   

  1. 1 Shaanxi Key Laboratory of Chemical Additives for Industry, College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xian 710021, China
    2 School of Civil Engineering, Central South University, Changsha 410075, China
  • Received: Revised: Online: Published:
  • Contact: Yang Bai, Hao Yao
  • Supported by:
    the National Natural Science Foundation of China(No. 21801162)
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H-shaped polymer is one type of polymer with light branched topological structure, which possesses unique rheological properties, bulk and solution assembly behaviors different from linear, star and hyperbranched polymers. In the recent years, researchers mainly focus on how to accurately construct H-shaped polymers due to their complex synthesis process. However, the literatures on H-shaped polymer and their properties are still limited and no review about them is reported. In this article, the synthesis and properties of H-shaped homopolymers, copolymers, terpolymers, quintopolymers and other H-shaped polymers are summarized according to the different building blocks of H-shaped polymers. On this basis, the research trends are also expected based on the progress of this kind of polymer.

Contents

1 Introduction

2 A2AA2-type homopolymer

3 A2BA2-type copolymer

4 A2BC2- and A(B)CA(B)-type terpolymer

5 A(B)CD(E)-type quintopolymer

6 Other H-shaped polymer

7 Conclusion and outlook

Key words: H-shaped polymer, branched polymer, H-shaped homopolymer, H-shaped copolymer, H-shaped terpolymer, H-shaped quintopolymer
Fig.1 The classification and structure of different H-shaped polymers
Fig.2 (a) Synthesis of A2AA2-typed H-shaped polymer;(b) Illustration of structures of the byproducts[9]
Fig.3 Aggregates obtained from the self-assembly of the H-shaped polymers with different chain-length ratio(A: Large-compound vesicles, B: Multilayer vesicles)[18]
Fig.4 Self-assembly and drug controlled release of H-terpolymer[41]
Fig.5 Synthesis of the A(B)CD(E)-typed polymer(PEG)(PMMA)-PtBA-(PCL)(PS) via one-pot double click reactions[42]
Fig.6 H-type supramolecular polymer based on host guest recognition[49]
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