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Progress in Chemistry 2020, Vol. 32 Issue (12): 1990-2003 DOI: 10.7536/PC200403 Previous Articles   Next Articles

• Review •

Catalytic Reductive Degradation of Cr(Ⅵ)

Honghong Wang1, Wen Lei1, Xiaojian Li1, Zhong Huang1, Quanli Jia2, Haijun Zhang1,**()   

  1. 1 The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
    2 Henan Key Laboratory of High Temperature Functional Ceramics, Zhengzhou University, Zhengzhou 450052, China
  • Received: Revised: Online: Published:
  • Contact: Haijun Zhang
  • Supported by:
    the National Natural Science Foundation of China(No. 51872210); the National Natural Science Foundation of China(51672194); the Key Program of Natural Science Foundation of Hubei Province, China(No. 2017CFA004); and the Program for Innovative Teams of Outstanding Young and Middle-Aged Researchers in the Higher Education Institutions of Hubei Province(No. T201602)
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With the rapid development of industrialization, the discharge of wastewater containing hexavalent chromium(Cr(Ⅵ)) is increasing day by day. The toxicity and high mobility of Cr(Ⅵ) cause great environmental pollution. Reducing Cr(Ⅵ) to trivalent chromium(Cr(Ⅲ)) with low toxicity and low fluidity is one of the current effective treatment methods. Compared with the traditional methods, the catalytic reduction of Cr(Ⅵ) driven by sunlight, electricity and microwave, has the advantages of no catalyst consumption, less reductant consumption, no secondary pollution and limited resource loss, and has become an effective solution to deal with Cr(Ⅵ) pollution. Based on this, the present paper reviews the application of photocatalyst, electrocatalyst and microwave catalyst for Cr(Ⅵ) reduction. Based on the summary and analysis of previous research results, the research direction and key points of Cr(Ⅵ) catalytic reduction technology in the future are prospected.

Contents

1 Introduction

2 Photocatalyst

2.1 Morphology control

2.2 Surface modification

2.3 Ion doping

2.4 Introduction of defect

2.5 Composite material

3 Electrocatalyst

3.1 Electrochemical catalyst

3.2 Piezoelectric catalyst

4 Photo-electrocatalyst

5 Microwave catalyst

5.1 Microwave enhanced catalyst

5.2 Microwave induced catalyst

6 Conclusion and outlook

Key words: Cr(Ⅵ), catalytic reduction, photocatalyst, electrocatalyst, photo-electrocatalyst, microwave catalyst
Fig.1 Schematic illustration of mechanism of a photocatalytic process[51]
Fig.2 TiO 2 nanostructures: (a) P25 nanoparticles[57];(b) nanosheets[58];(c) nanowires[53];(d) nanoflowers[60]
Fig.3 Photocatalytic reduction of Cr(Ⅵ) by TiO 2-Au/Pt[32]
Fig.4 The photocatalytic reduction mechanism of Cr(VI) by (a) Me xS y/MIL-125(Ti)[54] and(b) MIL-53(Fe)/CQDs[65]
Fig.5 The mechanism of photocatalytic reduction of Cr(Ⅵ) by (a) $TiO_{2}-HNO_{3}$[73] and (b) Fe-THWO3[74]
Fig.6 Preparation of RP 0.01TiO 2 and its mechanism of photocatalytic reduction of Cr(Ⅵ)[77]
Fig.7 The energy band diagram of the photocatalytic-system of g-C 3N 4/GO/BiFeO 3 heterostructures[52]
Fig.8 Preparation of C-SO 3H/CN-TiO 2 and its mechanism of photocatalytic reduction of Cr(Ⅵ)[80]
Fig.9 Mechanism of electrocatalytic reduction of Cr(Ⅵ) and oxidation of BPA by PGAs[21]
Fig.10 Mechanism of Cr(Ⅵ) reduction at FeS@rGO decorated cathode in MFC[18]
Fig.11 Mechanism of piezo-catalytic removal of Cr(Ⅵ) and 4-CP by Au/BiVO4[83]
Fig.12 The photoelectrocatalytic removal of Cr(Ⅵ) and acid red 1 by Ni foam@ZnO@ZnFe-LDH[89]
Fig.13 Mechanism of Cr(Ⅵ) reduction in MW/MoS 2-MnFe 2O 4 system[22]
Fig.14 Mechanism of Cr(Ⅵ) reduction in MW/Fe 3O 4@PANI system[19]
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Abstract

Catalytic Reductive Degradation of Cr(Ⅵ)