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Progress in Chemistry 2020, Vol. 32 Issue (9): 1307-1315 DOI: 10.7536/PC200222 Previous Articles   Next Articles

• Review •

Interface Modification Strategy of Basalt Fiber Reinforced Resin Matrix Composites

Hang Jia1, Yue Qiao1, Yu Zhang1, Qingxin Meng1, Cheng Liu1,**(), Xigao Jian1   

  1. 1. Department of Polymer Science and Materials, School of Chemical Engineering, Dalian University of Technology,Dalian 116024, China
  • Received: Revised: Online: Published:
  • Contact: Cheng Liu
  • Supported by:
    the National Natural Science Foundation of China(91860204); the Dalian Science and Technology Innovation Fund Project(2018J12GX055)
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In recent years, both industry and academia have been focusing their attention toward the development of sustainable natural fiber composites. Basalt fiber(BF) is a kind of green, environmentally friendly natural high-performance inorganic fiber, which has the advantages of high strength, high modulus, high temperature resistance, acid and alkali resistance, heat and sound insulation, good thermal vibration stability, excellent dielectric properties, and low cost. And the basalt fiber reinforced polymer(BFRP) composites are widely used in aircraft, automobiles, ships, construction, petrochemical pipelines, and wind turbine blades, due to their excellent mechanical properties and designability. However, the poor compatibility between BF and polymer matrix leads to many defects and deficiencies in BFRP composites, and the insufficient interface strength and the fragile interface phase have been the bottlenecks restricting the development of basalt fiber reinforced resin-based composites. Therefore, various physical or chemical treatment methods have been developed to treat BF surface by investigators in order to enhance the interface interaction between BF and resins, thus improving the interface binding capacity of BFRP composites. The main research directions about BFRP composites and several common mechanisms of composite interface interaction are introduced. Furthermore, the research work on the interface reinforcement of BFRP composites in recent years is reviewed in detail. Finally, current problems and future perspectives are discussed.

Contents

1 Introduction

2 Interface mechanism of resin-based composites

2.1 Wettability theory

2.2 Chemical bond theory

2.3 Mechanical bonding theory

3 Research progress of BFRPC interface modification

3.1 Acid-base treatment

3.2 Silane coupling agent treatment

3.3 Nanoparticle modification

3.4 Plasma treatment

3.5 CVD modification

4 Conclusion and outlook

Key words: basalt fiber, resin-based composites, interface mechanism, interfacial modification
Table 1 Performance comparison of basalt fiber, carbon fiber and E-glass fiber[5,7,13~15]
Properties BF CF E-GF
Density(g/cm3) 2.6~2.8 1.7~2.2 2.5~2.6
Temperature(℃) -260~700 -50~2000 -60~350
Thermo-conductivity(W/m·K) 0.031~0.038 5~185 0.034~0.040
Volume resistivity(Ω·m) 1×1012 2×10-5 1×1011
Sound-absorption coefficient(%) 0.9~0.99 - 0.8~0.93
Elastic modulus(GPa) 79.3~93.1 230~600 72.5~75.5
Tensile strength(MPa) 3000~4000 3500~6000 3100~3800
Diameter(μm) 5~25 5~10 5~30
Elongation to fracture(%) 1.5~3.2 1.3~2.0 2.7~3.0
Fig.1 Coupling mechanisms of common silane coupling agent
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